37464-86-1

Basic information

• Product Name: 4-Penten-1-ol,5-phenyl-
• Synonyms: 1-Hydroxy-5-phenylpent-4-ene; 5-Phenyl-4-penten-1-ol
• CAS NO: 37464-86-1
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.2283
• Mol File: 37464-86-1.mol
• Article Data: 37

Chemical Properties

• Boiling Point: 279.3°Cat760mmHg
• Flash Point: 122.5°C
• Density: 1.008g/cm³
• CAS DataBase Reference: 4-Penten-1-ol,5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Penten-1-ol,5-phenyl-(37464-86-1)
• EPA Substance Registry System: 4-Penten-1-ol,5-phenyl-(37464-86-1)

Safety Data

• Hazardous Substances Data: 37464-86-1(Hazardous Substances Data)

Upstream product

• 24595-58-2 5-phenylpent-4-yn-1-ol 
• 110-87-2 3,4-dihydro-2H-pyran 
• 100-52-7 benzaldehyde 
• 87436-78-0 (4-hydroxybutyl)-triphenylphosphonium bromide 
• 137472-41-4 threo-2-hydroxyphenylmethyl-1,1-dimethyl-1-silacyclopentane 
• 137472-41-4 erythro-2-hydroxyphenylmethyl-1,1-dimethyl-1-silacyclopentane 
• 17920-83-1 (4Z)-5-phenylpent-4-enoic acid 
• 144270-76-8 (Z)-5-phenylpent-4-enenitrile 
• 162754-70-3 1-methyl-1-(phenylethynyl)silacyclobutane 
• 137472-45-8 erythro-2-<1-hydroxy(phenyl)methyl>-1-isopropoxy-1-methylsilacyclopentane 
• 137472-39-0 1-<(Z)-1,2-epoxy-2-phenylethyl>-1-methylsilacyclobutane 
• 536-74-3 phenylacetylene 
• 162754-74-7 1-methyl-1-<(Z)-2-phenylethenyl>silacyclobutane 
• 4440-01-1 lithium phenylacetylide 

Downstream Products

• 51758-25-9 5-phenylpent-4-en-1-al 
• 37464-87-2 (5-bromopent-1-enyl)benzene 
• 10521-91-2 5-phenylpentan-1-ol 
• 32346-57-9 erythro-1-phenyl-1,2,5-pentanetriol 
• 852247-67-7 4,4-dimethyl-2-(5-phenyl-pent-4-enyl)-4H-isoquinoline-1,3-dithione 
• 428453-40-1 N-(4-toluenesulfonyl)-(Z)-5-phenylpent-4-enylamine 
• 106657-30-1 Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester 
• 39545-99-8 2-phenylcyclopent-2-enone 
• 14469-83-1 (5-bromopentyl)benzene 
• 31150-72-8 S-acetyl 5-phenylpentanethiol 
• 1027174-39-5 3-Oxo-4-(5-phenyl-pentylsulfanyl)-butyric acid methyl ester 
• 1026241-60-0 3-Cyano-3-hydroxy-4-(5-phenyl-pentylsulfanyl)-butyric acid methyl ester 
• 99896-08-9 8-phenylindolizidine 
• 144220-38-2 trans-N-allyl-N-(benzenesulfenyl)-5-phenylpent-4-enylamine 

Relevant articles and documents

Organocatalytic, Organic Oxidant Promoted, Enamine C?H Oxidation/Cyclopropanation Reaction

Herein, we demonstrate that organic, single-electron oxidant in the presence of diarylprolinol silylether type catalyst serves as a tool for the transformation of electron-rich enamines to iminium ions. These iminium ions take part in a subsequent Michael-initiated ring-closure (MIRC) reaction with in situ present nucleophile giving rise to overall cyclopropanation reaction of saturated aldehydes. Stereodefined cyclopropanes are obtained in high yields and selectivities. This one-pot transformation represents the additional example of saturated aldehydes being used in the coupled one-pot processes. (Figure presented.).

Rh(I)-catalyzed ring-opening of cyclobutanols via C–C bond activation: Synthesis of cis-olefin with a remote aldehyde

A Rh(I)-catalyzed ring-opening of cyclobutanols has been developed with ring opening products bearing cis-olefin and a remote aldehyde. Various substrates bearing different substituted aryl groups, heterocyclic groups and alkyl groups were compatible with

Pd(II)-Catalyzed [4 + 2] Heterocyclization Sequence for Polyheterocycle Generation

A new Pd(II)-catalyzed cascade sequence for the formation of polyheterocycles, from simple starting materials, is reported. The sequence is applicable to both indole and pyrrole substrates, and a range of substituents are tolerated. The reaction is thought to proceed by a Pd(II)-catalyzed C-H activated Heck reaction followed by a second Pd(II)-catalyzed aza-Wacker reaction with two Cu(II)-mediated Pd(0) turnovers per sequence. The sequence can be considered a formal [4 + 2] heterocyclization.