3753-58-0

Basic information

• Product Name: Phenol, 4-methoxy-, benzenesulfonate
• Synonyms: 4-methoxyphenyl benzenesulfonate
• CAS NO: 3753-58-0
• Molecular Formula: C₁₃H₁₂O₄S
• Molecular Weight: 264.29698
• Mol File: 3753-58-0.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Phenol, 4-methoxy-, benzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4-methoxy-, benzenesulfonate(3753-58-0)
• EPA Substance Registry System: Phenol, 4-methoxy-, benzenesulfonate(3753-58-0)

Safety Data

• Hazardous Substances Data: 3753-58-0(Hazardous Substances Data)

Upstream product

• 4106-18-7 1-(phenylsulfonyl)-1H-benzo[d][1,2,3]triazole 
• 150-76-5 4-methoxy-phenol 
• 98-09-9 benzenesulfonyl chloride 
• 65750-37-0 (2H)-p-methoxyphenol 
• 96875-66-0 N-nitroso-p-methoxy-benzenesulfonanilide 
• 3313-84-6 4-nitrophenyl benzenesulfonate 
• 63082-07-5 4-methoxy-phenylcarbamate 
• 7471-26-3 N-(4-methoxyphenyl)benzenesulphonamide 
• 62790-87-8 4-(tert-butyldimethylsilyloxy)anisole 
• 133745-75-2 N-fluorobis(benzenesulfon)imide 

Downstream Products

• 54660-04-7 N-(4-methoxyphenyl)pyrrolidine 
• 84736-52-7 (+/-)-(2R,4S)-4-tert-butyl-2-(4'-methoxyphenyl)cyclohexanone 
• 53040-92-9 4-(4-tolyl)anisole 
• 613-37-6 4-methoxylbiphenyl 
• 874-90-8 4-methoxybenzonitrile 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 150-76-5 4-methoxy-phenol 

Relevant articles and documents

NFSI/KF mediated mild and chemoselective interconversion of aryl TBDMS ethers to their benzene sulfonate

A one pot protocol for the transformation of aryl TBDMS ethers to corresponding benzene sulfonate esters using NFSI (N-flurobenzenesulfonimide)/KF is described. In situ generation of benzenesulfonyl fluoride directs chemoselective cleavage of aryl silyl ethers over alkyl silyl ethers. Electron withdrawing substituent's on aryl ring provided better yield than donating groups. Protecting groups and sensitive functionalities are well tolerated in this methodology. Thus, commercially available inexpensive reagents, mild reaction conditions and step economy are the advantages of this method.

Highly efficient Pd-catalyzed cyanation of aryl chlorides and arenesulfonates with potassium ferrocyanide in aqueous media

A highly improved Pd-catalyzed cyanation of aryl chlorides to corresponding benzonitriles was demonstrated in aqueous media. Moreover, Pd-catalyzed cyanation of aryl tosylates and benzenesulfonates with K4[Fe(CN) 6] was developed under the similar conditions, which extended application scope of the cyanation. Graphical Abstract: [Figure not available: see fulltext.]

Room-Temperature Ni(0)-Catalyzed Cross-Coupling Reactions of Aryl Arenesulfonates with Arylboronic Acids

Room-temperature Ni(0)-catalyzed cross-coupling reactions of aryl arenesulfonates with arylboronic acids are described. The Ni(0) catalyst, derived from Ni(COD)2 and PCy3, proved to be a general one for the Suzuki?Miyaura cross-coupling of a variety of aryl arenesulfonates. The mild reaction condition, the readily availability of the catalyst, and excellent coupling yields make aryl arenesulfonates potentially useful substrates in organic synthesis. Copyright