37531-27-4

Basic information

• Product Name: 1,1-dioxo-6-phenylsulfanyl-1,2,3,4-tetrahydro-1λ⁶-benzo[1,2,4]thiadiazine-7-sulfonic acid amide
• Synonyms: 1,1-dioxo-6-phenylsulfanyl-1,2,3,4-tetrahydro-1λ⁶-benzo[1,2,4]thiadiazine-7-sulfonic acid amide
• CAS NO: 37531-27-4
• Molecular Weight: 371.462
• Mol File: 37531-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-dioxo-6-phenylsulfanyl-1,2,3,4-tetrahydro-1λ⁶-benzo[1,2,4]thiadiazine-7-sulfonic acid amide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dioxo-6-phenylsulfanyl-1,2,3,4-tetrahydro-1λ⁶-benzo[1,2,4]thiadiazine-7-sulfonic acid amide(37531-27-4)
• EPA Substance Registry System: 1,1-dioxo-6-phenylsulfanyl-1,2,3,4-tetrahydro-1λ⁶-benzo[1,2,4]thiadiazine-7-sulfonic acid amide(37531-27-4)

Safety Data

• Hazardous Substances Data: 37531-27-4(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 58-93-5 6-chloro-3,4-dihydro-2H-1,2,4-benzothiadiazine-7-sulfonamide 1,1-dioxide 
• 58-94-6 chlorothiazide 
• 50-00-0 formaldehyd 
• 37531-26-3 4-amino-6-phenylsulfanyl-benzene-1,3-disulfonic acid diamide 

Relevant articles and documents

Achieving Nickel Catalyzed C-S Cross-Coupling under Mild Conditions Using Metal-Ligand Cooperativity

A simple and efficient approach of C-S cross-coupling of a wide variety of (hetero)aryl thiols and (hetero)aryl halides under mild conditions, mostly at room temperature, catalyzed by well-defined singlet diradical Ni(II) catalysts bearing redox noninnocent ligands is reported. Taking advantage of ligand centered redox events, the high-energetic Ni(0)/Ni(II) or Ni(I)/Ni(III) redox steps were avoided in the catalytic cycle. The cooperative participation of both nickel and the coordinated ligands during oxidative addition/reductive elimination steps allowed us to perform the catalytic reactions under mild conditions.