37608-93-8Relevant articles and documents
Direct Synthesis of Ketones from Primary Alcohols and 1-Alkenes
Jun, Chul-Ho,Huh, Chan-Woo,Na, Sang-Jin
, p. 145 - 147 (1998)
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KOtBu/DMSO Catalytic System for Isomerization of Allylic Alcohols to Ketones
Sai, Masahiro
, (2022/04/03)
The isomerization of allylic alcohols is an important reaction because it can afford carbonyl compounds in an atom-economical manner. Although base-catalyzed methods are more desirable than those using transition-metal catalysts from both the economic and environmental points of view, these methods have several drawbacks, such as narrow substrate scope and high catalyst loading. This paper reports the development of an efficient KOtBu/DMSO catalytic system suitable for the isomerization of a broad range of allylic alcohols with good yields, to which previously reported systems could not be applied. This catalytic system was successfully applied to a tandem allylic isomerization/electrophilic trapping reaction, thereby highlighting its synthetic utility.
Diels-Alder route to norbornane derived vicinal phosphane/borane frustrated Lewis pairs for the metal-free catalytic hydrogenation of α, β-unsaturated ketones
W?lke, Christian,Daniliuc, Constantin G.,Kehr, Gerald,Erker, Gerhard
supporting information, (2019/08/26)
The [4+2] cycloaddition reaction of the (dimesitylphosphino)cyclopentadienes 5a,b with N-phenylmaleimide gave the norbornene derivative 9. Its reduction with LiAlH4 produced the N-phenylpyrrolidino-annulated system 10. Treatment with Piers' bor
