37628-27-6

Basic information

• Product Name: Phosphonic acid, [phenyl(trimethylsilyl)methyl]-, diethyl ester
• CAS NO: 37628-27-6
• Molecular Formula: C14H25O3PSi
• Molecular Weight: 300.41
• Mol File: 37628-27-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [phenyl(trimethylsilyl)methyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [phenyl(trimethylsilyl)methyl]-, diethyl ester(37628-27-6)
• EPA Substance Registry System: Phosphonic acid, [phenyl(trimethylsilyl)methyl]-, diethyl ester(37628-27-6)

Safety Data

• Hazardous Substances Data: 37628-27-6(Hazardous Substances Data)

Upstream product

• 1080-32-6 O,O-diethyl benzylphosphonate 
• 17903-41-2 phenyl(trimethylsilyl)methyl bromide 
• 122-52-1 triethyl phosphite 

Downstream Products

• 87763-17-5 [1-(Butane-1-sulfinyl)-1,2-diphenyl-ethyl]-phosphonic acid diethyl ester 
• 87762-84-3 2-(Diethoxyphosphoryl)-3,6-dihydro-4,5-dimethyl-2-phenyl-2H-thiopyran 1-Oxide 
• 87763-00-6 [(Butane-2-sulfinyl)-phenyl-methyl]-phosphonic acid diethyl ester 
• 87762-99-0 [(Butane-1-sulfinyl)-phenyl-methyl]-phosphonic acid diethyl ester 
• 87763-18-6 1-(Diethoxyphosphoryl)-1,2-diphenylethene 
• 87762-98-9 (Diethoxyphosphoryl)phenylmethyl Methyl Sulfoxide 
• 87763-12-0 C₁₈H₂₀OS 
• 87763-14-2 C₁₈H₂₀OS 
• 73774-46-6 Z- and E-1-methylsulphinyl-1,2-diphenylethylene 
• 87762-68-3 (Diethoxyphosphoryl)phenylsulfine 
• 13058-24-7 tert-butoxytrimethylsilane 

Relevant articles and documents

A One Step Generation of α-Lithiotrimethylsilylalkanephosphonates. A New Preparative Route to Dialkyl 1-(Trimethylsilyl)alkanephosphonates and Vinylphosphonates

Chlorotrimethylsilane phosphonoalkylation in the presence of lithium diisopropylamide (LDA) in excess leads to the generation of an α-silyl α-phosphonyl carbanion which can be protonated, alkylated or converted into vinylphosphonates.