3771-61-7Relevant articles and documents
Dioxime oxalates; new iminyl radical precursors for syntheses of N-heterocycles
Portela-Cubillo, Fernando,Lymer, James,Scanlan, Eoin M.,Scott, Jackie S.,Walton, John C.
supporting information; experimental part, p. 11908 - 11916 (2009/04/06)
Symmetrical and unsymmetrical dioxime oxalates were prepared by treatment of oximes with oxalyl chloride. UV photolysis of these precursors was found to be an atom-efficient way of generating iminyl radicals. The process was most efficient for dioxime oxalates having aryl substituents attached to their C{double bond, long}N bonds. The method was useful for EPR spectroscopic study of iminyl and iminoxyl radicals. Photolyses in toluene solution, of dioxime oxalates containing alkenyl acceptor groups, yielded unsaturated iminyl radicals that ring closed to afford 3,4-dihydro-2H-pyrroles in good yields. Dioxime oxalates with biphenyl substituents also released iminyl radicals that ring closed onto the aromatic acceptor groups and, in acetonitrile solution, this approach provided a useful and atom-efficient method of making substituted phenanthridines.
Solid-Liquid Phase-Transfer Catalysis without Solvent: Selective Mono- and Di-alkylation of Benzyl Methyl Ketone
Aranda, Alfonso,Diaz, Angel,Diez-Barra, Enrique,Hoz, Antonio de la,Moreno, Andres,Sanchez-Verdu, Prado
, p. 2427 - 2430 (2007/10/02)
The alkylation of benzyl methyl ketone 1 has been performed by phase-transfer catalysis without solvent.Excellent yields of mono- 2 and di-alkyl derivatives 3 and 4 were obtained through general, selective and mild conditions.
ALKYNYLATION OF ALIPHATIC AND ALIPHATIC-AROMATIC KETONES
Vasil'eva, E. V.,Auvinen, E. M.,Favorskaya, I. A.
, p. 1266 - 1268 (2007/10/02)
The alkynylation of a series of aliphatic and aliphatic-aromatic ketones was realized under the conditions of phase-transfer catalysis.As a result the following γ-acetylenic ketones were obtained: 3-Butyl-5-hexyn-2-one, 3-amyl-5-hexyn-2-one, 3-hexyl-5-hex