37854-15-2

Basic information

• Product Name: 2-bromo-3-phenyl-2-propenenitrile
• Synonyms: 2-bromo-3-phenyl-2-propenenitrile
• CAS NO: 37854-15-2
• Molecular Weight: 208.057
• Mol File: 37854-15-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-bromo-3-phenyl-2-propenenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-3-phenyl-2-propenenitrile(37854-15-2)
• EPA Substance Registry System: 2-bromo-3-phenyl-2-propenenitrile(37854-15-2)

Safety Data

• Hazardous Substances Data: 37854-15-2(Hazardous Substances Data)

Upstream product

• 1885-38-7 cinnamic nitrile 
• 3252-43-5 dibromoacetonitrile 
• 100-52-7 benzaldehyde 
• 19521-13-2 α,β-dibromo-β-phenylpropionitrile 
• 28000-59-1 α,α-diiodotoluene 

Downstream Products

• 116584-97-5 trans N-ethyl-2-phenyl-3-cyanoaziridine 
• 116584-97-5 cis N-ethyl-2-phenyl-3-cyanoaziridine 
• 144453-40-7 2-benzylidene-pent-4-enenitrile 
• 72676-31-4 (E)-3-phenylacrylonitrile-2-d 
• 79175-51-2 (Z)-2-dutereo-3-phenylacrylonitrile 
• 37854-25-4 2-Diethylamino-3-methylene-4-phenyl-cyclobut-1-enecarbonitrile 
• 37854-26-5 2,2'-Bis-diethylamino-1,1'-dimethyl-4,4'-diphenyl-bicyclobutyl-2,2'-diene-3,3'-dicarbonitrile 
• 37847-73-7 2-Diethylamino-3-methyl-4-phenyl-cyclobut-1-enecarbonitrile 
• 77643-62-0 1-Cyclohexyl-2,4-diphenyl-1H-pyrrole-3-carbonitrile 
• 77643-64-2 1-Benzyl-2,4-diphenyl-1H-pyrrole-3-carbonitrile 
• 77643-59-5 (Z)-3-tert-Butylamino-3-phenyl-acrylonitrile 
• 77643-58-4 3-(N-Isopropyl)amino-3-phenylpropanenitrile 
• 77643-56-2 β-(N-cyclohexylamino)cinnamonitrile 
• 77643-57-3 β-benzylamino-cinnamonitrile 

Relevant articles and documents

Reaction of α-halo organoindium reagents with carbonyl compounds and electron-deficient alkenes

A variety of α-halo organoindium reagents were prepared in situ from the reaction of gem-dihalo compounds with indium metal, and their reactions with carbonyl compounds and electron-deficient alkenes were examined. The reactions of simple 1,1-diiodoalkanes with indium metal gave no defined products but benzal iodide gave stilbene in a moderate yield. α-Halo organoindium reagents derived from α,α-dibromo carbonyl compounds gave oxiranes and cyclopropanes upon the reactions with aldehydes and alkenes, respectively. 3,3-Dichloropropenes reacted with aldehydes in the presence of indium metal to give the corresponding chlorohydrins and/or homoallylalcohols, depending on the structures of both the dichloropropenes and aldehydes employed.

Addition de cyano-2 aziridines a quelques alcynes; obtention de pyrroles

Addition of the α-bromocinnamonitrile to primary amines (Cromwell method) leads to 2-cyano-3-phenyl-N-alkyl-aziridines, but the formation of the isomeric enamines always competes with this reaction.These aziridines, which are potential azomethine-ylids, a