37918-84-6

Basic information

• Product Name: 4-(3-phenylbut-3-en-1-yl)morpholine
• Synonyms: 4-(3-phenylbut-3-en-1-yl)morpholine
• CAS NO: 37918-84-6
• Molecular Weight: 217.311
• Mol File: 37918-84-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(3-phenylbut-3-en-1-yl)morpholine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3-phenylbut-3-en-1-yl)morpholine(37918-84-6)
• EPA Substance Registry System: 4-(3-phenylbut-3-en-1-yl)morpholine(37918-84-6)

Safety Data

• Hazardous Substances Data: 37918-84-6(Hazardous Substances Data)

Upstream product

• 54600-30-5 N-[(trimethylsilyl)methyl]morpholine 
• 19523-28-5 1-methyl-4-(2-phenyl-2-prop-2-ene-1-sulfonyl)-benzene 
• 110-91-8 morpholine 
• 2288-18-8 2-phenyl-1,3-butadiene 
• 50-00-0 formaldehyd 
• 98-83-9 isopropenylbenzene 

Relevant articles and documents

Intermolecular Hydroamination of 1,3-Dienes to Generate Homoallylic Amines

We report a Rh-catalyzed hydroamination of 1,3-dienes to generate homoallylic amines. Our work showcases the first case of anti-Markovnikov selectivity in the intermolecular coupling of amines and 1,3-dienes. By tuning the ligand properties and Br?nsted acid additive, we find that a combination of rac-BINAP and mandelic acid is critical for achieving anti-Markovnikov selectivity.