3796-69-8

Basic information

• Product Name: 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-, (5Z,9Z)-
• Synonyms: FEMA No. 3442,(5Z,9Z);(9E)-6,10,14-trimethyl-5,9,13-pentadecatrien-2-one;Farnesyl acetone,(5Z,9Z);5,9,13-Pentadecatrien-2-one,6,10,14-trimethyl-,(5Z,9Z);cis,cis-Farnesylacetone
• CAS NO: 3796-69-8
• Molecular Formula: C18H30O
• Molecular Weight: 262.436
• Mol File: 3796-69-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 372.8±21.0 °C(Predicted)
• Density: 0.866±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-, (5Z,9Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-, (5Z,9Z)-(3796-69-8)
• EPA Substance Registry System: 5,9,13-Pentadecatrien-2-one, 6,10,14-trimethyl-, (5Z,9Z)-(3796-69-8)

Safety Data

• Hazardous Substances Data: 3796-69-8(Hazardous Substances Data)

Upstream product

• 59905-15-6 dehydronerolidol 
• 3796-70-1 trans geranyl acetone 
• 50994-69-9 potassium Z-2-methyl-1,3-butadienylsulfinate 
• 86948-89-2 (E)-2-Acetyl-6-(3,7-dimethyl-octa-1,6-diene-3-sulfonyl)-5-methyl-hex-4-enoic acid tert-butyl ester 
• 86948-98-3 3,7-Dimethyl-3-((Z)-2-methyl-buta-1,3-diene-1-sulfonyl)-octa-1,6-diene 
• 92747-33-6 methyl (E)-2-methyl-6-oxo-2-heptenyl carbonate 
• 53254-60-7 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene 
• 112162-99-9 3-Oxo-butyric acid (E)-1,5,9-trimethyl-1-vinyl-deca-4,8-dienyl ester 
• 86948-99-4 (E)-7-(3,7-Dimethyl-octa-1,6-diene-3-sulfonyl)-6-methyl-hept-5-en-2-one 
• 22842-11-1 (5Ξ,9E)-6,10,14-trimethyl-pentadeca-5,9,13-trien-1-yne 

Downstream Products

• 1331771-17-5 (11E)-(4,8,12,16-tetramethylheptadeca-3,7,11,15-tetraenyl)benzene 
• 502-69-2 6,10,14-Trimethyl-2-pentadecanon 
• 13955-75-4 (6S,10R)-6,10,14-trimethylpentadecan-2-one 
• 16825-16-4 (6R,10R)-6,10,14-trimethylpentadecan-2-one 

Relevant articles and documents

-SIGMATROPIC REARRANGEMENTS OF THE ACETOACETATES OF ALLYL ALCOHOLS (CARROLL REACTION) AND ALLYLPHENYL ETHERS (CLAISEN REACTION) ON THE SURFACE OF ADSORBENTS

A method has been developed for effecting rearrangements of allylacetoacetates to γ,δ-unsaturated ketones (Carroll rearrangement) and allylaryl ethers to the corresponding allylphenols (Claisen rearrangement) under conditions of adsorption on aluminum oxide and silica gel.The method provides a sharp reduction of the temperature of these reactions and improvement of their efficiency.

Allylic Carbonates. Efficient Allylating Agents of Carbonucleophiles in Palladium-Catalyzed Reactions under Neutral Conditions

Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phospine catalyst.Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.