37994-87-9

Basic information

• Product Name: 1-Adamantyl ethyl carbonate
• Synonyms: 1-Adamantyl ethyl carbonate
• CAS NO: 37994-87-9
• Molecular Weight: 224.3
• Mol File: 37994-87-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Adamantyl ethyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Adamantyl ethyl carbonate(37994-87-9)
• EPA Substance Registry System: 1-Adamantyl ethyl carbonate(37994-87-9)

Safety Data

• Hazardous Substances Data: 37994-87-9(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 5854-52-4 1-adamantyl chloroformate 
• 62087-82-5 1-adamantylfluoroformate 

Relevant articles and documents

Solvolysis-Decomposition of 1-Adamantyl Chloroformate: Evidence for Ion Pair Return in 1-Adamantyl Chloride Solvolysis

In hydroxylic solvents, 1-adamantyl chloroformate reacts with loss of carbon dioxide and formation of both solvolysis and decomposition products.The rates of both processes are appreciably sensitive to solvent ionizing power, with the solvolysis slightly more so.The influence of anionic additives is discussed.For mixtures of hydroxylic solvents, the selectivities for the formation of solvolysis products are very similar to those observed in conventional solvolyses of 1-adamantyl derivatives.It is suggested that 1-Ad+Cl- ion pair intermediates are formed, and the observation of collapse requires that an identical collapse, corresponding to internal return, also occurs in 1-adamantyl chloride solvolysis.A comparison with solvolyses of other 1-AdOCOX compounds suggests that the initial ionization is not to 1-Ad+(OCOCl)- and that the 1-Ad+Cl- ion pair is formed either in a concerted process or via a very unstable (1-AdOCO)+Cl- ion pair.