38059-15-3

Basic information

• Product Name: Benzene, 1,1'-methylenebis[2-iodo-
• Synonyms: 2,2'-diiododiphenylmethane;1-Iodo-2-(2-iodobenzyl)benzene;bis-(2-iodo-phenyl)-methane;Di(2-iodophenyl)methane;Benzene,1,1'-methylenebis[2-iodo
• CAS NO: 38059-15-3
• Molecular Formula: C13H10I2
• Molecular Weight: 420.02700
• Mol File: 38059-15-3.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 403.1±25.0 °C(Predicted)
• Density: 1.972±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, 1,1'-methylenebis[2-iodo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-methylenebis[2-iodo-(38059-15-3)
• EPA Substance Registry System: Benzene, 1,1'-methylenebis[2-iodo-(38059-15-3)

Safety Data

• Hazardous Substances Data: 38059-15-3(Hazardous Substances Data)

Upstream product

• 41634-35-9 10H-dibenzo[b,e]iodininium; iodide 

Downstream Products

• 192137-75-0 (AuP(C₆H₅)3)3(C₆H₄CH₂C₆H₄)⁽¹⁺⁾*BF₄^(1-)=[(AuP(C₆H₅)3)3(C₆H₄CH₂C₆H₄)]BF₄ 
• 175546-69-7 μ-1,2-(diphenylphosphino)ethane-bis-aurio(2,2'-diphenylmethane) 
• 165544-55-8 1,1'-methylenebis-<2-(phenylethynyl)benzene> 
• 28662-84-2 1,2,3,8-tetrahydro-1,3-diphenyl-8-dibenzazulenone 
• 1634-74-8 di-o-tolylmethane 
• 180057-59-4 1-iodo-2-{[(2-phenylethynyl)phenyl]methyl}benzene 
• 21993-96-4 9-phenyl-9,10-dihydro-9-silaanthracene 
• 25187-02-4 o,o'-diiodobenzophenone 

Relevant articles and documents

Electron Transfer from a Cyclic Diaryliodine Species to Arenediazonium Salts. Evidence for the Intermediacy of 9-I-2 Structure in Inodine Atom Transfer Reactions

2,2′-Diiodobiphenyl (1) reacts with arenediazonium hexafluorophosphates (ArN2+PF6- ) in acetonitrile to form biphenyleneiodonium salt (4) and iodoarenes (ArI) as major products. The reaction follows a free-radical-chain mechanism and involves a cyclic diaryliodine, 9-I-2 species (3), which is trapped as the iodonium salt (4) by a single-electron transfer (SET) to the diazonium salt. The results show that diaryliodine intermediates formed by the addition of phenyl radicals to iodoarenes can have sufficient lifetimes to allow trapping bv bimolecular processes.