38068-98-3

Basic information

• Product Name: 6-(4-methoxyphenyl)fulvene
• Synonyms: 6-(4-methoxyphenyl)fulvene
• CAS NO: 38068-98-3
• Molecular Weight: 184.238
• Mol File: 38068-98-3.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 6-(4-methoxyphenyl)fulvene(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(4-methoxyphenyl)fulvene(38068-98-3)
• EPA Substance Registry System: 6-(4-methoxyphenyl)fulvene(38068-98-3)

Safety Data

• Hazardous Substances Data: 38068-98-3(Hazardous Substances Data)

Upstream product

• 14774-77-7 p-methoxyphenyllithium 
• 542-92-7 cyclopenta-1,3-diene 
• 68-12-2 N,N-dimethyl-formamide 
• 136618-41-2 E-2'-p-methoxystyryl iodide 
• 1066-54-2 trimethylsilylacetylene 
• 696-62-8 para-iodoanisole 
• 74-86-2 acetylene 
• 77-73-6 dicyclopentadiene 
• 123-11-5 4-methoxy-benzaldehyde 
• 130248-50-9 (E)-1,3-bis(trimethylsilyl)-6-(4-methoxyphenyl)fulvene 
• 15719-64-9 methylammonium carbonate 
• 16733-97-4 cyclopentadienyllithium 

Downstream Products

• 77979-10-3 4-[1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-2-methyl-1,3-diphenyl-2,4-dihydro-cyclopenta[c]pyrrole 
• 77979-09-0 (4E)-5,6-Dihydro-4-(4-methoxyphenyl)methylen-2-methyl-1,3-diphenyl-4H-cyclopentapyrrol 
• 77979-11-4 7-(4-Methoxyphenyl)methylen-2,5-dimethyl-1,3,4,6-tetraphenyl-7H-cyclopenta<1,2-c:3,4-c'>dipyrrol 
• 905280-36-6 bis-[di-(p-methoxyphenyl)methylcyclopentadienyl] titanium(IV) dichloride 

Relevant articles and documents

Kinetics and Mechanism of Pyrrolidine Buffer-Catalyzed Fulvene Formation

Rapid synthesis of fulvenes is achieved using pyrrolidinium/pyrrolidine buffers in anhydrous acetonitrile. Time-dependent UV-vis absorption and NMR spectroscopy reveal that the rate and yield of fulvene formation depend strongly on both the presence of acid in the medium and the choice of solvent, and they are negatively affected by water. Kinetic data have been collected for various substrates, and the synthetic benefits of the adjusted reaction conditions are showcased. Enhancements of reaction rates are found in comparison to literature procedures. α-Unsaturated fulvenes that were previously difficult to access can now be obtained in good yields.

GROUP 3 METAL COMPOUNDS AND USE THEREOF IN THE TREATMENT OF SOLID TUMORS

The present invention relates to the compounds of Formula 1 wherein M is Sc or Y, Hal is CI, Br, F or I R is alkyl with 1 - 4 atoms of C X is CI, Br, F or I or a group such as that shown hereinafter wherein R is alkyl with 1 - 4 atoms of C and the use thereof in the treatment of solid tumors.

Asymmetric Pentafulvene Carbometalation - Access to Enantiopure Titanocene Dichlorides of Biological Relevance

Unprecedented asymmetric copper-catalyzed addition of ZnEt2 (ZnBu2) to the exocyclic C=C bond of pentafulvenes C5H4(=CHAr) (Ar=2-MeOPh and related species) results in enantiomerically enriched (up to 93:7 e.r.)