38147-72-7

Basic information

• Product Name: 5,6-diphenylimidazo[2,1-a]isoquinoline
• Synonyms: 5,6-diphenylimidazo[2,1-a]isoquinoline
• CAS NO: 38147-72-7
• Molecular Weight: 320.393
• Mol File: 38147-72-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5,6-diphenylimidazo[2,1-a]isoquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-diphenylimidazo[2,1-a]isoquinoline(38147-72-7)
• EPA Substance Registry System: 5,6-diphenylimidazo[2,1-a]isoquinoline(38147-72-7)

Safety Data

• Hazardous Substances Data: 38147-72-7(Hazardous Substances Data)

Upstream product

• 670-96-2 2-Phenylimidazole 
• 501-65-5 diphenyl acetylene 

Relevant articles and documents

Nickel-catalyzed oxidative C-H/N-H annulation of N-heteroaromatic compounds with alkynes

The reaction of N-heteroaromatic compounds, such as 2-aryl-pyrrole, benzimidazole, imidazole, indole, and pyrazole derivatives, with alkynes in the presence of a catalytic amount of a nickel complex results in C-H/N-H oxidative annulation. The reaction shows a high functional group compatibility. While both Ni(0) and Ni(ii) complexes show a high catalytic activity, Ni(0) is proposed as a key catalytic species in the main catalytic cycle. In the case of the Ni(ii) system, the presence of a catalytic amount of a strong base, such as KOBut, is required for the reaction to proceed. In sharp contrast, a base is not required in the case of the Ni(0) system. The proposed mechanism is supported by DFT studies.

Metal complexes

The present invention relates to metal complexes and to electronic devices, in particular organic electroluminescent devices, comprising these metal complexes.

Fluorescent naphthyl- and anthrylazoles from the catalytic coupling of phenylazoles with internal alkynes through the cleavage of multiple C-H bonds

(Chemical Equation Presented) Bright light rings: The direct coupling of phenylazoles with an internal alkyne proceeds efficiently in the presence of a rhodium catalyst and a copper oxidant to selectively give either the 1-naphthyl- or 1-anthrylazole derivatives through the cleavage of multiple C-H bonds (see scheme; 1-naphthylazole derivative not shown). Some of the products exhibit intense fluorescence in the solid state.