38152-41-9

Basic information

• Product Name: 1,2-bis(4-methoxyphenyl)ethane-1,2-diol bis(trimethylsilyl ether)
• Synonyms: 1,2-bis(4-methoxyphenyl)ethane-1,2-diol bis(trimethylsilyl ether)
• CAS NO: 38152-41-9
• Molecular Weight: 418.681
• Mol File: 38152-41-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,2-bis(4-methoxyphenyl)ethane-1,2-diol bis(trimethylsilyl ether)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-bis(4-methoxyphenyl)ethane-1,2-diol bis(trimethylsilyl ether)(38152-41-9)
• EPA Substance Registry System: 1,2-bis(4-methoxyphenyl)ethane-1,2-diol bis(trimethylsilyl ether)(38152-41-9)

Safety Data

• Hazardous Substances Data: 38152-41-9(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 123-11-5 4-methoxy-benzaldehyde 
• 4656-04-6 bis(trimethylsilyl)mercury 
• 4464-76-0 1,2-bis(4-methoxyphenyl)-1,2-ethanediol 

Downstream Products

• 4464-76-0 1,2-bis(4-methoxyphenyl)-1,2-ethanediol 
• 66768-20-5 (R,R)-(+)-1,2-bis(4-methoxyphenyl)ethane-1,2-diol 
• 122798-27-0 (-)-(2S,3S)-1,2-bis(4-methoxyphenyl)ethane1,2-diol 
• 17258-75-2 Tetrachlorohydroquinone bis(trimethylsilyl) ether 
• 123-11-5 4-methoxy-benzaldehyde 
• 107-46-0 Hexamethyldisiloxane 
• 7677-24-9 trimethylsilyl cyanide 

Relevant articles and documents

Reaction of (η2-arylaldehyde)nickel(0) complexes with Me3SiX (X=OTf, Cl). Application to catalytic reductive homocoupling reaction of arylaldehyde

Arylaldehydes can coordinate to nickel(0) in η2-fashion to give η2-arylaldehydenickel complexes, which react with Me3SiOTf or Me3SiCl to give η1:η1-siloxybenzylnickel or η3-silox

Samarium iodide-catalyzed pinacol coupling of carbonyl compounds

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Synthesis of Pinacol Silylethers from Aromatic Aldehydes via α-Siloxybenzyliron Complexes

Quantitative synthesis of pinacol ethers 4, 2 (X = H, Me, OMe or Cl) from the α-siloxybenzyliron complexes, 3 is reported.The iron dimer, 5 was the only other product which was reused for the reaction.