38186-40-2Relevant articles and documents
Dimesitylboryl-functionalized fluorene derivatives: Promising luminophors with good electron-transporting ability for deep blue organic light-emitting diodes
Xu, Xiaofei,Ye, Shanghui,He, Bairong,Chen, Bin,Xiang, Jiayun,Zhou, Jian,Lu, Ping,Zhao, Zujin,Qiu, Huayu
, p. 136 - 141 (2014)
Two dimesitylboryl-functionalized fluorene derivatives are synthesized and characterized. They show deep blue fluorescence in both solution and film states, with narrow spectral profiles and excellent solid-state emission efficiencies up to 94%. Due to th
Two novel neutral and ionic Ir(iii) complexes based on the same bipolar main ligand: A comparative study of their photophysical properties and applications in solution-processed red organic light-emitting diodes
Du, Jin,Huang, Wei,Liao, Rui,Sun, Huibin,Wang, Jianpu,Wang, Nana,Wang, Xiumei,Wang, Ying
supporting information, p. 11310 - 11315 (2020/07/21)
Using 4-(5-(4-(dimesitylboranyl)phenyl)pyridin-2-yl)-N,N-diphenylaniline (BNpppy) as a cyclometalated ligand, 1,10-phenanthroline or 2,4-pentanedione (acac) as the ancillary ligand, respectively, two novel iridium(iii) complexes (Ir-1 and Ir-2) were succe
Di-(2-picolyl)-N-(2-quinolinylmethyl)amine-Functionalized Triarylboron: Lewis Acidity Enhancement and Fluorogenic Discrimination Between Fluoride and Cyanide in Aqueous Solution
Yuan, Mao-Sen,Du, Xianchao,Liu, Zhiqiang,Li, Tianbao,Wang, Wenji,Anslyn, Eric V.,Wang, Jinyi
, p. 9211 - 9216 (2018/07/06)
Triarylboron-based Lewis acids as fluoride sensors face a stimulating academic challenge because of the high hydration enthalpy of fluoride, and are usually influenced by a competing response for cyanide ion. Herein, we present a new triarylborane functionalized by a metal-ion ligand, di-(2-picolyl)-N-(2-quinolinylmethyl)amine, with subsequent metalation. In aqueous solution, this triarylborane (QB) can capture fluoride and cyanide anions through chelation induced by the synergy of boron and metal ions. Moreover, this triarylborane moiety acts as a fluorescent reporter of the binding, allowing for discrimination between fluoride and cyanide anions through dual-channel fluorescence changes. The different chelation models and fluorogenic responses of this sensor toward F? and CN? were verified by the single-crystal structures of 2-to-2 adduct for KCN and 1-to-1 for KF.