38227-84-8

Basic information

• Product Name: Piperidine, 2,6-dimethyl-, lithium salt
• CAS NO: 38227-84-8
• Molecular Formula: C7H15N.Li
• Molecular Weight: 119.136
• Mol File: 38227-84-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Piperidine, 2,6-dimethyl-, lithium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 2,6-dimethyl-, lithium salt(38227-84-8)
• EPA Substance Registry System: Piperidine, 2,6-dimethyl-, lithium salt(38227-84-8)

Safety Data

• Hazardous Substances Data: 38227-84-8(Hazardous Substances Data)

Upstream product

• 766-17-6 (2R,6S)-2,6-dimethylpiperidine 
• 4111-54-0 lithium diisopropyl amide 
• 881-42-5 diphenylmethyllithium 

Downstream Products

• 93948-24-4 2,6-Dimethyl-1-(naphth-2-yl-methyl)-piperidin 
• 91-57-6 2-Methylnaphthalene 
• 17037-71-7 N-benzoyl-cis-2,6-dimethylpiperidine 
• 766-17-6 (2R,6S)-2,6-dimethylpiperidine 
• 4111-54-0 lithium diisopropyl amide 
• 108-67-8 1,3,5-trimethyl-benzene 

Relevant articles and documents

LITHIUM DIALKYLAMIDES. 13C PARAMETERS AND SLOW PROTON TRANSFER

The changes in 13C chemical shifts for the structural change R2NH -> R2N-Li have been measured for a series of dialkylamines.These lithiation shifts are largest at the alpha carbon (3.7-9.7 ppm) and decrease in the order α > β > χ > δ.The rates of lithium-hydrogen interchange between R2NH and R'2N-Li have been determined.The activation energies are large (9 - 17 kcal/mole) and increase as the size of R or R' increases.The slow exchange permits the direct measurement of acidity differences between pairs of amines using 13C nmr.