38274-86-1

Basic information

• Product Name: 2-Bromotricyclo[8.2.2.24,7]hexadecane-1(12),4,6,10,13,15-hexene
• Synonyms: 2-Bromotricyclo[8.2.2.24,7]hexadeca-4,6,10,12(1),13,15-hexene;2-Bromotricyclo[8.2.2.24,7]hexadecane-1(12),4,6,10,13,15-hexene
• CAS NO: 38274-86-1
• Molecular Formula: C₁₆H₁₅Br
• Molecular Weight: 287.1943
• Mol File: 38274-86-1.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Bromotricyclo[8.2.2.24,7]hexadecane-1(12),4,6,10,13,15-hexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromotricyclo[8.2.2.24,7]hexadecane-1(12),4,6,10,13,15-hexene(38274-86-1)
• EPA Substance Registry System: 2-Bromotricyclo[8.2.2.24,7]hexadecane-1(12),4,6,10,13,15-hexene(38274-86-1)

Safety Data

• Hazardous Substances Data: 38274-86-1(Hazardous Substances Data)

Upstream product

• 1633-22-3 [2.2]Paracyclophan 

Downstream Products

• 101717-45-7 dimethyl-[4-(4-methyl-trans-styryl)-benzyl]-amine 
• 100765-00-2 C₂₄H₂₂N₂O₂S 

Relevant articles and documents

Metal-free catalytic hydrogenation of imines with recyclable [2.2]paracyclophane-derived frustrated lewis pairs catalysts

A series of [2.2]paracyclophane-derived frustrated Lewis pairs (FLPs) with reversible, metal-free hydrogen activation was synthesized and successfully applied in the hydrogenation of imines in moderate to good yields. The high stability of the novel FLP system enables effective recycling of the metal-free catalysts. This reaction could also be compatible with a larger scale and developed into a pharmaceutical synthesis of cinacalcet {(R)-N-[1-(1-naphthyl) ethyl]-3-[3-(trifluoromethyl)phenyl]propan-1-amine} without heavy metal residues.

Cyclophanes, 26 On the Functionalisation of the Ethano Bridges of Paracyclophane

An improved procedure for the syntheses of paracyclophan-1-ene (4) is described.Addition of halogen to this olefin, subsequent dehydrohalogenation, and again addition and elimination provides a wide range of bridge-halogenated cyclophanes.The derivat