38476-60-7Relevant articles and documents
Rhodium-Catalyzed Insertion Reaction of PhP Group of Pentaphenylcyclopentaphosphine with Acyclic and Cyclic Disulfides
Arisawa, Mieko,Sawahata, Kyosuke,Yamada, Tomoki,Sarkar, Debayan,Yamaguchi, Masahiko
, p. 938 - 941 (2018)
Organophosphorus compounds with a phosphorus atom attached to a phenyl group and two organothio/organoseleno groups were synthesized using the rhodium-catalyzed insertion reaction of the PhP group of pentaphenylcyclopentaphosphine (PhP)5 with acyclic disulfides and diselenides. The method was applied to the synthesis of heterocyclic compounds containing the S-P-S group by the reaction of (PhP)5 and cyclic disulfides such as 1,2-dithietes, 1,2-dithiocane, 1,4,5-dithiopane, and 1,2-dithiolanes.
REACTION OF PHENYLSULFENYL CHLORIDE WITH C-(N,N-DIMETHYLAMINO)-METHYLENE-P-PHENYLPHOSPHINE
Ionkin, A. S.,Nikolaeva, N. V.,Arbuzov, B. A.
, p. 843 - 844 (2007/10/02)
PhSCl adds regiospecifically to the P=C double bond in C-(N,N-dimethylamino)-methylene-P-phenylphosphine to give PhP(SPh)2 and Cl2CHNMe2.