3848-26-8Relevant articles and documents
Preparation method of longicorn sex pheromone 2, 3-diketone series compounds and derivatives thereof
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, (2021/04/21)
The invention discloses a preparation method of longhorn beetle sex pheromone 2, 3-diketone compounds, which comprises the following steps: by using linear carboxylic acid containing 6, 8 and 10 carbons as a raw material, carrying out carboxylic acid [alpha]- halogenation, elimination, reduction and the like to synthesize a series of 2, 3-diketone compounds, and carrying out reduction and chiral resolution on the structure to obtain a series of [alpha]-hydroxy ketone chiral compounds. The route has the characteristics of safety, easiness in operation, simple post-treatment, high yield and low cost.
High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones
Suda, Kohji,Baba, Kenji,Nakajima, Shin-Ichiro,Takanami, Toshikatsu
, p. 2570 - 2571 (2007/10/03)
Iron(III) tetraphenylporphyrin triflate, Fe(tpp)OTf, works as an efficient and characteristic Lewis acid catalyst in the selective rearrangement of α,β-epoxy ketones into 1,2-diketones.
Catalytic oxidative cleavage of electrophilic double bonds
Huang,Khrapov,Hansen,Idoux,Gupton
, p. 2709 - 2722 (2007/10/02)
Oxidative cleavage of a variety of electrophilic double bond substrates has been effected under mild reaction conditions by sodium metaperiodate or sodium hypochlorite catalyzed by ruthenium oxide.