3848-34-8Relevant articles and documents
EFFETS MICELLAIRES SUR LA BASICITE ET LA REACTIVITE DE NUCLEOPHILES α AROMATIQUES
Meyer, G.,Viout, P.
, p. 2269 - 2272 (1981)
The oximation of p-nitrophenylacetate by benzaldoximates in aqueous solution is catalyzed by CTAB micelles.The catalysis is more effective when the base strength of the oximate decreases; the reactivity of benzaldoximates is not dependent on their basicity.Our data may be interpreted in terms of orbital-controlled reactions, with interactions between both the n and ? occupied orbitals of the oximates and the LUMO of the acetate.