38491-40-6

Basic information

• Product Name: phenyl-(2,3,3-trichloro-allyl)-sulfide
• Synonyms: phenyl-(2,3,3-trichloro-allyl)-sulfide
• CAS NO: 38491-40-6
• Molecular Weight: 253.58
• Mol File: 38491-40-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenyl-(2,3,3-trichloro-allyl)-sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl-(2,3,3-trichloro-allyl)-sulfide(38491-40-6)
• EPA Substance Registry System: phenyl-(2,3,3-trichloro-allyl)-sulfide(38491-40-6)

Safety Data

• Hazardous Substances Data: 38491-40-6(Hazardous Substances Data)

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 110-80-5 2-ethoxy-ethanol 
• 99282-97-0 phenyl-(β,β,β,β'-tetrachloro-isopropyl)-sulfide 
• 21400-25-9 1,1,2-trichloropropene 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 10436-39-2 1,1,2,3-Tetrachloropropene 
• 930-69-8 sodium thiophenolate 
• 28124-18-7 2-bromo-3,3,3-trichloro-propene 
• 6066-14-4 3-bromo-1,1,2-trichloro-propene 

Downstream Products

• 120110-74-9 C₂₁H₁₇ClS₃ 
• 78399-87-8 phenyl-(2,3,3-trichloro-allyl)-sulfone 

Relevant articles and documents

SYNTHESIS OF ORGANOSULFUR COMPOUNDS FROM TRICHLOROALLYL ALCOHOL

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FREE-RADICAL REACTIONS OF 1,1,2-TRICHLOROPROPENE. III. FREE-RADICAL THIYLATION OF TRICHLOROPROPENE BY DIARYL DISULFIDES

The reaction of CCl2=CClCH3 with ArSSAr (Ar = 4-ClC6H4, C6H5, 4-CH3C6H4), initiated by UV irradiation, in a quartz flask leads to the formation of a mixture of isomeric sulfides ArSC(CH3)=CCl2 and cis- and trans-ArSCCl=CClCH3 and also the sulfides ArSCH2CCl=CCl2 and ArSCCl2CCl2CH3.In addition, significant amounts of the products from oxidation and oligomerization of trichloropropene CH3CCl2COOH, CCl2=CClCH2CCl=CClCH2Cl, and CCl2=CClCH2CCl2CCl2CH3 are formed.The oligomerization of trichloropropene is almost completely suppressed in molybdenum glass.A reaction mechanism involving the formation of the radicals ArSC(CH3)ClC.Cl2 and ArSCCl2C.ClCH3 and the allyl radical .CH2CCl=CCl2 is proposed.