38584-43-9

Basic information

• Product Name: adamantan-1-yl benzoate
• Synonyms: adamantan-1-yl benzoate
• CAS NO: 38584-43-9
• Molecular Weight: 256.345
• Mol File: 38584-43-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: adamantan-1-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: adamantan-1-yl benzoate(38584-43-9)
• EPA Substance Registry System: adamantan-1-yl benzoate(38584-43-9)

Safety Data

• Hazardous Substances Data: 38584-43-9(Hazardous Substances Data)

Upstream product

• 768-95-6 1-adamanthanol 
• 36967-85-8 benzoyl triflate 
• 768-94-5 1-Adamantanamine 
• 65-85-0 benzoic acid 
• 1579-72-2 2,2,2-trifluoroethyl benzoate 
• 1934-92-5 N-methyl-N-phenyl-benzamide 
• 108-86-1 bromobenzene 
• 201230-82-2 carbon monoxide 
• 98-88-4 benzoyl chloride 
• 768-93-4 1-iodoadamantane 
• 6597-18-8 (dibenzoyloxyiodo)benzene 
• 281-23-2 adamantane 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Protecting-group-free synthesis of hydroxyesters from amino alcohols

The synthesis of hydroxyesters from carboxylic acids and unprotected amino alcohols in both continuous flow and batch processes is reported. The formation of a transient diazonium species with a dinitrite reagent is key in this transformation. The reaction conditions are compatible with a variety of functional groups.

Kinetic Modeling of the Nickel-Catalyzed Esterification of Amides

Nickel-catalyzed coupling reactions provide exciting tools in chemical synthesis. However, most methodologies in this area require high catalyst loadings, which commonly range from 10-20 mol % nickel. Through an academic-industrial collaboration, we demonstrate that kinetic modeling can be used strategically to overcome this problem, specifically within the context of the Ni-catalyzed conversion of amides to esters. The successful application of this methodology to a multigram-scale coupling, using only 0.4 mol % Ni, highlights the impact of this endeavor.

4-(N,N -dimethylamino)pyridine hydrochloride as a recyclable catalyst for acylation of inert alcohols: Substrate scope and reaction mechanism

4-(N,N-Dimethylamino)pyridine hydrochloride (DMAP·HCl), a DMAP salt with the simplest structure, was used as a recyclable catalyst for the acylation of inert alcohols and phenols under base-free conditions. The reaction mechanism was investigated in detail for the first time; DMAP·HCl and the acylating reagent directly formed N-acyl-4-(N′,N′-dimethylamino) pyridine chloride, which was attacked by the nucleophilic substrate to form a transient intermediate that released the acylation product and regenerated the DMAP·HCl catalyst.