38614-36-7 Usage
Description
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is an organomagnesium reagent with the chemical formula (CH3)2C=CHMgBr, commonly used in various chemical reactions due to its nucleophilic addition properties.
Uses
Used in Organic Synthesis:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used as a reagent for the preparation of biaryls, alkylarenes, alkenylarenes, and alkynylalkenones, facilitating the formation of these compounds through nucleophilic addition reactions.
Used in Palladium-Catalyzed Coupling Reactions:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used as a reagent in the study of palladium-catalyzed coupling with aryl tosylates, enabling the formation of new chemical bonds and the synthesis of complex organic molecules.
Used in Pharmaceutical Synthesis:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used in the synthesis of (2S,3S)-3′-fluoroisoleucine, a compound with potential pharmaceutical applications.
Used in Research and Development:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used in research and development for studying various chemical reactions and developing new synthetic methods in the field of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 38614-36-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,6,1 and 4 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 38614-36:
(7*3)+(6*8)+(5*6)+(4*1)+(3*4)+(2*3)+(1*6)=127
127 % 10 = 7
So 38614-36-7 is a valid CAS Registry Number.
38614-36-7Relevant articles and documents
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Tenneti, Srinivasarao,Biswas, Souvagya,Cox, Glen Adam,Mans, Daniel J.,Lim, Hwan Jung,RajanBabu
supporting information, p. 9868 - 9881 (2018/07/25)
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce
Bridgehead Reactivity, Nucleophilic and Radical Additions, and Lithium Aluminum Hydride Reduction of 1-(Arylsulfonyl)bicyclobutanes: General Access to Substituted, Functionalized Cyclobutanes. Syntheses of (+/-)-Citrilol Acetate, (+/-)-Junionone, and the
Gaoni, Yehiel,Tomazic, Alenka
, p. 2948 - 2957 (2007/10/02)
A general approach to the synthesis of a wide range of substituted cyclobutane derivatives is based on two specific reactions of 1-(arylsulfonyl)bicyclobutanes (1) and on some general reactions of the bicyclobutane ring systems.One specific cyclobutane fo
