387339-00-6

Basic information

• Product Name: 4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol
• Synonyms: 4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol
• CAS NO: 387339-00-6
• Molecular Weight: 554.263
• Mol File: 387339-00-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol(387339-00-6)
• EPA Substance Registry System: 4-{4-(chloromethyl-dimethyl-silanyl)-1,1-bis-[3-(chloromethyl-dimethyl-silanyl)-propyl]-butyl}-phenol(387339-00-6)

Safety Data

• Hazardous Substances Data: 387339-00-6(Hazardous Substances Data)

Upstream product

• 3144-74-9 chloromethyldimethylsilane 
• 224191-80-4 4-triallylmethylphenol 

Downstream Products

• 1135927-28-4 C₃₄H₅₅Cl₃OSi₃ 
• 1008425-09-9 C₂₈H₄₉Cl₃O₂Si₃ 
• 527698-54-0 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenol 
• 387339-01-7 4-{4-(azidomethyldimethylsilanyl)-1,1-bis-[3-(azidomethyldimethylsilanyl)propyl]butyl}phenol 
• 387339-02-8 4-{4-(aminomethyl-dimethyl-silanyl)-1,1-bis-[3-(aminomethyl-dimethyl-silanyl)-propyl]-butyl}-phenol 

Relevant articles and documents

Click assemblies and redox properties of arene- and gold-nanoparticle-cored triazolylbiferrocene-terminated dendrimers

Large dendritic assemblies terminated by organometallic groups that possess a rich redox chemistry and stability in two or more oxidation states are highly desired as electron-reservoir systems, sensors, and redox catalysts. Here the synthesis and click (CuAAC) chemistry of ethynyl biferrocene including branching onto dendrons, arene-cored dendrimers, and gold nanoparticles are developed, and the role of the 1,2,3-triazole linkers and redox chemistry of these assemblies are discussed including the properties and stabilities of the redox states.

Convergent dendron approach using a phenol triallyl building block: Synthesis of a phenol dendron containing 27 allyl termini

A successful convergent dendron synthesis is achieved using a phenol triallyl (AB3) building block by a sequence of reactions consisting of hydrosilylation-phenol protection. The key feature is the hydrosilylation using dimethylchloromethylsilane that avoids the side dehydrohalogenation previously found with linear branches containing β-hydrogens. The advantage of the AB3 building block is the multiplication of the dendron branches by three at each generation, which allows the synthesis of the second-generation 27-allyl phenol dendron.

Gold nanoparticles containing redox-active supramolecular dendrons that recognize H2PO4-

Gold nanoparticles have been functionalized with thiol dendrons containing three redox active amidoferrocenyl or silylferrocenyl units; using cyclic voltammetry, these dendronized gold nanoparticles recognize H2PO4-.