38764-58-8

Basic information

• Product Name: 4-methyl-N-(oxodiphenyl-λ⁶-sulfaneylidene)benzene sulfonamide
• Synonyms: 4-methyl-N-(oxodiphenyl-λ⁶-sulfaneylidene)benzene sulfonamide
• CAS NO: 38764-58-8
• Molecular Weight: 371.481
• Mol File: 38764-58-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 4-methyl-N-(oxodiphenyl-λ⁶-sulfaneylidene)benzene sulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-(oxodiphenyl-λ⁶-sulfaneylidene)benzene sulfonamide(38764-58-8)
• EPA Substance Registry System: 4-methyl-N-(oxodiphenyl-λ⁶-sulfaneylidene)benzene sulfonamide(38764-58-8)

Safety Data

• Hazardous Substances Data: 38764-58-8(Hazardous Substances Data)

Upstream product

• 945-51-7 1,1'-sulfinylbisbenzene 
• 24698-06-4 S-p-nitrophenyl-S-phenyl-N-tosylsulfilimine 
• 473-34-7 N,N-dichloro-p-toluenesulfonamide 
• 89538-92-1 N-(4-methylbenzenesulfonyl) phenyl sulfonimidoyl chloride 
• 71-43-2 benzene 
• 139-66-2 diphenyl sulfide 
• 70-55-3 toluene-4-sulfonamide 
• 591-51-5 phenyllithium 
• 22731-83-5 S,S-diphenylsulphoximine 
• 933-00-6 p-methylbenzenesulfenyl chloride 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 91378-37-9 S,S-diphenyl-(N-p-tolylfulfinyl)sulfoximine 
• 91378-34-6 S,S-diphenyl-N-(4-methylphenylthio)sulfoximine 
• 13150-76-0 N-[(4-methylphenyl)sulfonyl]-S,S-diphenyl-sulfilimine 

Relevant articles and documents

Copper-catalyzed imination of sulfoxides and sulfides

Sulfoximines and sulfilimines have attracted considerable interest among organic chemists. The Cu(II)-catalyzed imination of sulfoxides and sulfides using various N-fluoro benzenesulfonamides was investigated in this study. The scope of the reaction was demonstrated by using several substituted sulfides and sulfoxides. The flow strategy for the preparation of NH-sulfoximines was also examined. By trapping nitrene intermediates through triphenylphosphine, we found that the reaction was conducted through a metal-nitrene intermediate mechanism.

A versatile and highly reactive polyfluorinated hypervalent iodine (III) compound

(Figure Presented) Hyper-reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one-pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well-established reactions (e.g. C-C bond cleavage and the conversion of alcohols into aldehydes).

Facile conversion of sulfilimines into sulfoximines using dioxiranes

Employing dimethyldioxirane, the direct conversion of several N-(p-tolylsulfonyl)sulfilimines and of one N-(acetyl)sulfilimine into the corresponding sulfoximines was achieved in high yield under mild conditions. Optically active S-(p-tolyl)-S-methyl-N-(p