38851-76-2

Basic information

• Product Name: Phosphine, methyl-1-naphthalenylphenyl-
• CAS NO: 38851-76-2
• Molecular Formula: C17H15P
• Molecular Weight: 250.28
• Mol File: 38851-76-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phosphine, methyl-1-naphthalenylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, methyl-1-naphthalenylphenyl-(38851-76-2)
• EPA Substance Registry System: Phosphine, methyl-1-naphthalenylphenyl-(38851-76-2)

Safety Data

• Hazardous Substances Data: 38851-76-2(Hazardous Substances Data)

Upstream product

• 55123-94-9 (+/-)-methyl(1-naphthyl)phenylphosphine oxide 
• 34585-11-0 chloro-(1-naphthalenyl)-phenylphosphine 
• 676-58-4 methylmagnesium chloride 
• 4073-31-8 (diethylamino)phenylchlorophosphine 
• 644-97-3 Dichlorophenylphosphine 
• 708-90-7 (N,N-diethylamino)(methyl)(phenyl)phosphine 
• 20684-97-3 chloro(diisopropylamino)(phenyl)phosphine 
• 703-55-9 1-naphthylmagnesiumbromide 
• 15849-86-2 methyl(phenyl)chlorophosphine 
• 506-82-1 dimethylcadmium 

Downstream Products

• 55123-94-9 (+/-)-methyl(1-naphthyl)phenylphosphine oxide 
• 24153-87-5 Benzyl-methyl-naphthalen-1-yl-phenyl-phosphonium; bromide 
• 19432-40-7 Benzylmethyl(1-naphthyl)phenylphosphonium-chlorid 
• 254100-64-6 C₃₃H₄₆NO₃PSSi 
• 37775-99-8 (R)-methyl-(1-naphthyl)(phenyl)phosphine oxide 
• 37775-92-1 (S_P*)-methyl-(1-naphthyl)phenylphosphine oxide 
• 19432-37-2 Benzylidene-methyl-naphthalen-1-yl-phenyl-λ⁵-phosphane 
• 84673-94-9 (2S,3S)-2,3-Bis-benzoyloxy-3-carboxy-propionatebenzyl-methyl-naphthalen-1-yl-phenyl-phosphonium; 
• 1351376-58-3 dichloro(η6-p-cymene)[(R)-methyl(1-naphthyl)phenylphosphine]ruthenium(II) 
• 1243265-61-3 chloro(η3-1,3-diphenylallyl)[(R)-methyl(1-naphthyl)phenylphosphane]palladium(II) 
• 1243265-41-9 (η3-2-methylallyl)bis[(R)-methyl(1-naphthyl)phenylphosphane]palladium(II) hexafluorophosphate 
• 868948-45-2 chloro(η3-2-methylallyl)[(R)-methyl(1-naphthyl)phenylphosphine]palladium(II) 
• 868948-55-4 chloro[(R)-methyl(1-naphthyl)phenylphosphine](η3-1-phenylallyl)palladium(II) 
• 94249-62-4 RuCH₃(CO)2(C₆H₅P(OCH₃)(CH(CH₃)2))(P(CH₃)3)2⁽¹⁺⁾*BF₄^(1-)=(RuCH₃(CO)2(C₆H₅P(OCH₃)(CH(CH₃)2))(P(CH₃)3)2)(BF₄) 

Relevant articles and documents

FACILE REDUCTION OF ORGANIC HALIDES AND PHOSPHINE OXIDES WITH LiAlH4-CeCl3

A new reagent system, LiAlH4-CeCl3, exhibits powerful and characteristic reducing ability.Organic halides including fluorine compounds are smoothly dehalogenated with this reagent.Phosphine oxides are also reduced to phosphines in excellent yields.

A simple resolution procedure using the Staudinger reaction for the preparation of P-stereogenic phosphine oxides

The resolution of a variety of (±)-P-stereogenic phosphines is achieved by exploiting the Staudinger reaction of a (±)-phosphine with enantiopure (1S,2R)-O-(tert-butyldimethylsilyl)isobornyl-10-sulfonyl azide. The resulting mixtures of diastereomeric phosphinimines are generally separable by fractional crystallization or flash chromatography. Subsequent acid-catalyzed hydrolysis provides the corresponding optically pure phosphine oxides in high yields.

Reactions with Phosphine Alkylenes, XLI. Resolution of Chiral Phosphonium Salts

The preparation and resolution of chiral phosphonium salts 1a - c via the corresponding phosphonium ylides is described.