38858-81-0Relevant articles and documents
Lithium Nitropyrazolates as Potential Red Pyrotechnic Colorants
Dufter-Münster, Alicia M. W.,Harter, Alexander G.,Klap?tke, Thomas M.,Reinhardt, Elena,R?mer, Julia,Stierstorfer, J?rg
, (2022/02/09)
Strontium-based red pyrotechnic colorants have fallen into disrepute due to the harmful influence of this alkaline earth metal on adolescents. In this context, the energetic character, safety, and combustion to benign nitrogen gas of nitropyrazoles are used for the design of the corresponding lithiated materials, which are investigated as potential replacements in the current work. For this purpose, the lithium salts of 3,4-dinitro-1H-pyrazole, 3,5-dinitro-1H-pyrazole, 4-amino-3,5-dinitro-1H-pyrazole, 3,4,5-trinitro-1H-pyrazole, and 4-hydroxy-3,5-dinitro-1H-pyrazole were extensively characterized by standard analytical methods, low-temperature single-crystal X-ray diffraction, studies of the thermo-chemical behavior, and sensitivity assessments. Our assumption that the high nitrogen contents and the low oxygen balances of these compounds would adjust a cool, reductive flame atmosphere essential for red emissions by lithium was put to the test.
COMPOUNDS AND METHODS FOR KINASE MODULATION, AND INDICATIONS THEREFOR
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Paragraph 0321, (2017/02/24)
Compounds of Formula (I) or a pharmaceutically acceptable salt, a solvate, a tautomer, an isomer or a deuterated analog thereof, wherein A, J, R1, R2, R3, R4, R5, R6, R7, R9, X, m and n are as described herein, compositions thereof, and methods and uses thereof.
Synthetic method for 1-methyl-3,4,5-triaminopyrazole
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Paragraph 0004; 0007, (2016/11/09)
The invention relates to a synthetic method for a compound, especially to a s ynthetic method for 1-methyl-3,4,5-triaminopyrazole. The method uses 3-nitropyrazole as a raw material and prepares the target product through the following steps: nitration, thermal rearrangement, nitration, ammonification and methylation. The method has mild reaction conditions and high yield.