38860-01-4

Basic information

• Product Name: 1-tributylstannyl-4-trimethylsilylbenzene
• Synonyms: 1-tributylstannyl-4-trimethylsilylbenzene
• CAS NO: 38860-01-4
• Molecular Weight: 439.344
• Mol File: 38860-01-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-tributylstannyl-4-trimethylsilylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-tributylstannyl-4-trimethylsilylbenzene(38860-01-4)
• EPA Substance Registry System: 1-tributylstannyl-4-trimethylsilylbenzene(38860-01-4)

Safety Data

• Hazardous Substances Data: 38860-01-4(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 38860-02-5 (C₄H₉)2Sn{C₆H₄-p-Si(CH₃)3}2 
• 10035-10-6 hydrogen bromide 
• 18817-58-8 Sn{C₆H₄-p-Si(CH₃)3}4 
• 75-77-4 chloro-trimethyl-silane 
• 17151-49-4 (4-bromophenyl)tri-n-butylstannane 
• 1461-23-0 tributyltin bromide 
• 6999-03-7 1-bromo-4-(trimethylsilyl)benzene 
• 1067-52-3 tributyltin methoxide 
• 683-18-1 dibutyltin chloride 

Downstream Products

• 1461-25-2 tetra-n-butyltin(IV) 
• 768-32-1 trimethylphenylsilane 
• 960-16-7 tributylphenylstannane 
• 1461-22-9 tributyltin chloride 
• 1091-38-9 tributyl(4-vinylphenyl)stannane 
• 1095-99-4 (C₄H₉)3SnC₆H₄-p-CHCHC₂H₅ 
• 95135-20-9 (C₄H₉)3SnC₆H₄-p-CH₂CHCH₂ 
• 1093-08-9 (C₄H₉)3SnC₆H₄-p-C(CH₃)CH₂ 
• 1067-97-6 tributyltin hydroxide 
• 1045-56-3 tributyl(pentafluorophenyl)stannane 

Relevant articles and documents

A Sn atom-economical approach toward arylstannanes: Ni-catalysed stannylation of aryl halides using Bu3SnOMe

Stannylation of carbon-halogen bonds is one of the most promising and straightforward approaches for the preparation of organostannane compounds. Although a wide variety of methods are now available, all protocols require the use of highly nucleophilic organometals or wasteful stannyl sources like distannanes. Here, we report a new nickel-catalysed stannylation of aryl and alkenyl-halides using Bu3SnOMe as a stannyl source to afford aryl and vinyl-stannanes, respectively. This method enables the stannylation of not only bromides, but also chlorides and triflates to furnish functionalized aryl- and alkenyl-stannanes without the release of wasteful and toxic stannyl byproducts.