38940-36-2Relevant articles and documents
Highly Enantioselective Construction of Dihydrooxazines via Pd-Catalyzed Asymmetric Carboetherification
Li, Na,Sun, Baozhen,Liu, Shuang,Zhao, Jinbo,Zhang, Qian
supporting information, p. 190 - 193 (2020/01/02)
A straightforward synthesis of highly enantioenriched 5,6-dihydro-4H-1,2-oxazines is realized by Pd-catalyzed asymmetric carboetherification of γ,δ-alkenyl oximes with (hetero)aryl and alkenyl halides in the presence of a commercially available bisphosphine ligand. The enantioenriched products can be facilely converted to functionalized alcohols with high fidelity of chiral transfer.
Chiral AuI- and AuIII-Isothiourea Complexes: Synthesis, Characterization and Application
Gasperini, Danila,Greenhalgh, Mark D.,Imad, Rehan,Siddiqui, Shezaib,Malik, Anum,Arshad, Fizza,Choudhary, Muhammad Iqbal,Al-Majid, Abdullah M.,Cordes, David B.,Slawin, Alexandra M. Z.,Nolan, Steven P.,Smith, Andrew D.
supporting information, p. 1064 - 1075 (2019/01/04)
During an investigation into the potential union of Lewis basic isothiourea organocatalysis and gold catalysis, the formation of gold-isothiourea complexes was observed. These novel gold complexes were formed in high yield and were found to be air- and moisture stable. A series of neutral and cationic chiral gold(I) and gold(III) complexes bearing enantiopure isothiourea ligands was therefore synthesized and fully characterized. The steric and electronic properties of the isothiourea ligands was assessed through calculation of their percent buried volume and the synthesis and analysis of novel iridium(I)-isothiourea carbonyl complexes. The novel gold(I)- and gold(III)-isothiourea complexes have been applied in preliminary catalytic and biological studies, and display promising preliminary levels of catalytic activity and potency towards cancerous cell lines and clinically relevant enzymes.
Copper-catalyzed cyclization and azidation of γ,δ-unsaturated ketone O-benzoyl oximes
Su, Hailin,Li, Weifei,Xuan, Zhaoli,Yu, Wei
supporting information, p. 64 - 70 (2015/03/04)
An intramolecular imination/azidation sequence has been realized through the tetrakis(acetonitrile)copper(I) hexafluorophophate [Cu(CH3CN)4PF6]-catalyzed reaction of γ,δ-unsaturated ketone O-benzoyl oximes with trimethylsi