38988-92-0

Basic information

• Product Name: pinan-2α-yl methyl ether
• CAS NO: 38988-92-0
• Molecular Weight: 168.279
• Mol File: 38988-92-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pinan-2α-yl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: pinan-2α-yl methyl ether(38988-92-0)
• EPA Substance Registry System: pinan-2α-yl methyl ether(38988-92-0)

Safety Data

• Hazardous Substances Data: 38988-92-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 14575-88-3 2αH-pinan-3α-yl toluene-p-sulphonate 

Relevant articles and documents

Rearrangement of Pinane Derivatives. Part 8. Deamination of 2αH-Pinan-3α-ylamine

Solvolysis of 2αH-pinan-3α-yl toluene-p-sulphonate has been shown to proceed with concomitant 1,2-hydride shift to give the pinan-2-yl carbocation.Contrary to earlier reports, this species reacts normally to give, in good yield, pinan-2-yl substitution products.In contrast the pinan-3-ylamines react via a similar route, but give much smaller amounts of pinan-2-yl products.The usual reasons for differences between solvolysis and deamination (i.e. the intermediacy of diazonium ions and/or high-energy ions) can be discounted, and possible reasons for the differences in behaviour are discussed.