39014-35-2

Basic information

• Product Name: C₂H₄O₂*H⁽¹⁺⁾
• CAS NO: 39014-35-2
• Molecular Weight: 61.0605
• Mol File: 39014-35-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂H₄O₂*H⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂H₄O₂*H⁽¹⁺⁾(39014-35-2)
• EPA Substance Registry System: C₂H₄O₂*H⁽¹⁺⁾(39014-35-2)

Safety Data

• Hazardous Substances Data: 39014-35-2(Hazardous Substances Data)

Upstream product

• 107-31-3 Methyl formate 
• 146297-21-4 C₇H₇F*H⁽¹⁺⁾ 
• 138850-94-9 C₇H₇F*H⁽¹⁺⁾ 

Downstream Products

• 107-31-3 Methyl formate 
• 52809-63-9 C₇H₈*H⁽¹⁺⁾ 

Relevant articles and documents

A comparison of the relative binding energie of H(+) and NO(+) to aromatic and haloaromatic bases by high pressure mass spectrometry

Proton transfer equilibria (B1H(+) + B2 B1 + B2H(+)) and NO(+) transfer equilibria (B1NO(+) + B2 B1 + B2NO(+)) have been studied for the following bases B, benzene, toluene, o-, m-, and p-xylene.NO(+) transfer equilibria for fluoro- and chlorobenzene have also been studied.Pulsed electron beam, high-pressure ion source mass spectrometry has been used to obtain the equilibrium constant K and hence the free energy changes ΔG0 and from van't Hoff plots, ΔH0 and ΔS0.Entropy changes are in general much smaller for NO(+) transfer than for H(+) transfer but the magnitude of the changes in the proton affinity and NO(+) affinity of toluene caused by a fluorine substituent is about the same, even though the absolute value of the proton affinity is greater by a factor of 4.The position of the F substituent on toluene has a marked effect on proton affinity but no effect on NO(+) affinity.The latter appears to be responsive only to the inductive effect.