390381-02-9Relevant articles and documents
C(sp3)-H selective benzylic borylation by in situ reduced ultrasmall Ni species on CeO2
Yoshii, Daichi,Yatabe, Takafumi,Yabe, Tomohiro,Yamaguchi, Kazuya
, p. 2150 - 2155 (2021/02/20)
Herein, we report that highly dispersed Ni hydroxide species supported on CeO2 act as an efficient heterogeneous catalyst for the selective borylation of benzylic C(sp3)-H bonds of alkylarenes including secondary derivatives, using pinacolborane as the bo
Efficient synthesis of alkylboronic esters: Via magnetically recoverable copper nanoparticle-catalyzed borylation of alkyl chlorides and bromides
Shegavi, Mahadev L.,Agarwal, Abhishek,Bose, Shubhankar Kumar
supporting information, p. 2799 - 2803 (2020/06/17)
We report a magnetically separable Cu nanocatalyst (Fe-DOPA-Cu) for the borylation of alkyl halides with alkoxy diboron reagents, providing alkylboronic esters in high yields, with broad functional group tolerance under mild reaction conditions. The procedure is also applicable to the borylation of benzyl chlorides and bromides. Radical clock experiments support a radical-mediated process. Easy recycling of the catalyst resulted in no significant loss of activity up to ten runs.
Nickel-catalyzed borylation of arenes and indoles via C-H bond cleavage
Furukawa, Takayuki,Tobisu, Mamoru,Chatani, Naoto
supporting information, p. 6508 - 6511 (2015/04/14)
The first nickel-catalyzed method for the borylation of carbon-hydrogen bonds in arenes and indoles is described. The use of an N-heterocyclic carbene ligand is essential for an efficient reaction, with an N-cyclohexyl-substituted derivative being optimal. This method is readily applied to the gram scale synthesis of 2-borylindole.