39078-86-9Relevant articles and documents
Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides
Bi, Wen-Zhu,Zhang, Wen-Jie,Li, Zi-Jie,He, Yuan-Hao,Feng, Su-Xiang,Geng, Yang,Chen, Xiao-Lan,Qu, Ling-Bo
, p. 8701 - 8705 (2021/10/22)
A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.
Dithioallophanic Acids : Interaction of Carbon Oxysulphide with S-Benzyl-N-methylisothiocarbamide
Dravid, R. N.,Chande, M. S.
, p. 496 - 498 (2007/10/02)
Carbon oxysulphide reacts with S-benzyl-N-methylisothiocarbamide in cold benzene to afford products which are different from those obtained earlier in similar reactions.Methylthiocarbamide and thiocyanic acid adduct, an interesting product has been isolated.In addition to this S-benzyl-N-methylthiocarbamate, S-benzyl-N-methyldithiocarbamate and dibenzyl disulphide have also been isolated from the reaction mixture.The formation of these products from dithioallophanic acid intermediate is rationalised.
