39115-40-7Relevant articles and documents
Anthracene capped isobenzofuran: A synthon for the preparations of iptycenes and iptycene quinones
Pei, Bao-Jian,Chan, Wing-Hong,Lee, Albert W. M.
, p. 1774 - 1777 (2011/06/17)
Anthracene capped isobenzofuran 5 (5,6-(9,10-dihydroanthracen-9,10-yl) isobenzofuran) was synthesized for the first time. It is a highly reactive and versatile synthon for the synthesis of iptycene derivatives via Diels-Alder reactions. Cycloadducts 10 could be readily deoxygenated to iptycenes 11. Two new reactions of PhI(OAc)2/TfOH have been explored. Endoxides 10 were directly oxidized to iptycene quinones 12, and isobenzofuran 5 was conveniently converted to triptycene dialdehyde 16. H-shaped centrally extended pentiptycene quinones 13 and 14 were also synthesized.
Photoinduced Electron Transfer in meso-Triphenyltriptycenylporphyrin-Quinones. Restricting Donor-Acceptor Distances and Orientation
Wasielewski, Michael R.,Niemczyk, Mark P.
, p. 5043 - 5045 (2007/10/02)
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