39137-72-9Relevant articles and documents
Electrochemical Reduction of Alkyl Aryl and Dialkyl Trithiocarbonates
Falsig, Mogens,Lund, Henning
, p. 545 - 550 (2007/10/02)
Electrochemical reduction in aprotic medium of alkyl aryl trithiocarbonates (1a-c) in the presence of an alkylating agent gives tetraalkyltetrathioethylenes (2a-c); under similar conditions dialkyl trithiocarbonates (3a-c) also form 2, but the reaction is complicated by the ability of 3 to act as an alkylating agent.The mechanisms of the reactions are discussed on the basis of the preparative and cyclic voltammetric results.