3915-60-4

Basic information

• Product Name: Pyridine, 2-[(phenylmethyl)thio]-, 1-oxide
• CAS NO: 3915-60-4
• Molecular Formula: C12H11NOS
• Molecular Weight: 217.291
• Mol File: 3915-60-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-[(phenylmethyl)thio]-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-[(phenylmethyl)thio]-, 1-oxide(3915-60-4)
• EPA Substance Registry System: Pyridine, 2-[(phenylmethyl)thio]-, 1-oxide(3915-60-4)

Safety Data

• Hazardous Substances Data: 3915-60-4(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 100-53-8 phenylmethanethiol 
• 122333-43-1 1-Benzyloxy-1H-pyridine-2-thione 
• 62381-90-2 2-(phenylmethylsulfinyl)pyridine N-oxide 
• 2402-95-1 2-chloropyridine-N-oxide 
• 55791-06-5 benzyl mesylate 
• 3811-73-2 2-mercaptopyridine-1-oxide sodium salt 

Downstream Products

• 62381-90-2 2-(phenylmethylsulfinyl)pyridine N-oxide 

Relevant articles and documents

Copper pyrithione (CuPT)-catalyzed/mediated amination and thioarylation of (hetero)aryl halides: A competition

A facile method for the synthesis of N-arylheterocycles and di(hetero)aryl sulfides under mild condition is described. In these transformations, copper pyrithione (CuPT) was used as the copper catalyst for C─N coupling, while served as catalyst and coupled partner for C─S coupling with high yields and broad substrate tolerance. The S-arylation process was also utilized for the construction of valuable bioactive 2-sulfonylpyridine 1-oxide derivatives.

Generation of Sulfenate Salts via Ipso-substitution of Azaheterocyclic Sulfoxides. First Preparation and Characterization of Sodium 2-Pyridinesulfenate

2-Alkyl- or 2-aryl-sulfinylpyridine N-oxides undergo ipsosubstitution reaction with sodium ethoxide to afford sodium sulfenates which were converted soon to the corresponding sulfinates upon contact with oxygen.Sodium 2-pyridinesulfenate was prepared and characterized by FT-IR as the first example of stable sulfenate.