391928-94-2

Basic information

• Product Name: benzyl 3,4-dideoxy-α-L-glycero-pent-3-enopyranoside
• Synonyms: benzyl 3,4-dideoxy-α-L-glycero-pent-3-enopyranoside
• CAS NO: 391928-94-2
• Molecular Weight: 206.241
• Mol File: 391928-94-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: benzyl 3,4-dideoxy-α-L-glycero-pent-3-enopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 3,4-dideoxy-α-L-glycero-pent-3-enopyranoside(391928-94-2)
• EPA Substance Registry System: benzyl 3,4-dideoxy-α-L-glycero-pent-3-enopyranoside(391928-94-2)

Safety Data

• Hazardous Substances Data: 391928-94-2(Hazardous Substances Data)

Upstream product

• 391928-90-8 (2S)-2-benzyloxy-2H-pyran-3-(6H)-one 
• 856175-47-8 benzyl 2-O-acetyl-3,4-dideoxy-α-L-glycero-pent-3-enopyranoside 
• 476487-80-6 (R)-2-(benzyloxy)-2H-pyran-3(6H)-one 
• 476487-78-2 2,3,4-tri-O-acetyl-1,5-anhydro-L-erythro-pent-1-enitol 
• 113889-50-2 (3S,4R,5R)-2-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 28697-53-2 D-arabinopyranose 
• 30694-66-7 2,3,4-tri-O-acetyl-1,5-anhydro-D-erythro-pent-1-enitol 
• 100-51-6 benzyl alcohol 
• 51830-02-5 bromo-2,3,4-O-triacetyl-α/β-L-arabinopyranoside 
• 87-72-9 L-(+)-arabinose 
• 14125-76-9 1,5-anhydro-2,3,4-tri-O-acetyl-D-threo-pent-1-enitol 
• 62446-93-9 1,2,3,4-tetra-O-acetyl-D-xylopyranose 
• 87-72-9 D-Xylose 
• 5329-50-0 (-)-benzyl β-D-arabinopyranoside 

Downstream Products

• 5329-50-0 (-)-benzyl β-D-arabinopyranoside 
• 391928-90-8 (2S)-2-benzyloxy-2H-pyran-3-(6H)-one 

Relevant articles and documents

Stereoselective total synthesis of all the stereoisomers of (+)- and (?)-febrifugine and halofuginone

A convenient method for the total synthesis of all the stereoisomers of febrifugine and halofuginone using D-arabinose and L-arabinose as the key starting materials is reported. Apart from the inherent stereocenters in these pentose sugars, the method utilizes the selective hydrogenolysis of the anomeric O-benzyl group, stereoselective Grignard reaction and Wacker oxidation as the key steps to obtain the important precursors for the total synthesis.

Enantiospecific synthesis of both enantiomers of 2-benzyloxydihydropyran-3- ones from arabinose

Approaches to the enantioselective synthesis of the useful building blocks (2R)- and (2S)-2-benzyloxy-2(H)-pyran-3(6H)-one (12 and 17, respectively) are described. The most direct and highly yielding route for the synthesis of 12 was based on the 'one-pot