39248-95-8

Basic information

• Product Name: Benzenecarbothioic acid, 4-methyl-, S-(4-methylphenyl) ester
• CAS NO: 39248-95-8
• Molecular Formula: C15H14OS
• Molecular Weight: 242.342
• Mol File: 39248-95-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-methyl-, S-(4-methylphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-methyl-, S-(4-methylphenyl) ester(39248-95-8)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-methyl-, S-(4-methylphenyl) ester(39248-95-8)

Safety Data

• Hazardous Substances Data: 39248-95-8(Hazardous Substances Data)

Upstream product

• 7163-50-0 (4-methylphenyl)(oxo)acetic acid 
• 106-45-6 para-thiocresol 
• 99-94-5 p-Toluic acid 
• 619-55-6 para-methylbenzamide 
• 624-31-7 4-tolyl iodide 
• 106871-53-8 2-(p-tolylthio)-2-oxoacetic acid 
• 106-38-7 para-bromotoluene 
• 874-60-2 4-methyl-benzoyl chloride 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 106-42-3 para-xylene 
• 103-19-5 di(p-tolyl) disulfide 
• 350-42-5 4-methylbenzoyl fluoride 
• 14159-45-6 bis(p-tolylsulfonyl)diazomethane 
• 201230-82-2 carbon monoxide 

Downstream Products

• 6840-28-4 diphenyl(p-tolyl)phosphine oxide 
• 53144-71-1 4-methylphenylmethyl diphenylphosphine oxide 
• 23886-71-7 4-methoxy-4'-methylbenzophenone 
• 72818-32-7 (4-Methylbenzoyl)-4-tolyl-sulfon 
• 620-94-0 di-(p-tolyl)sulfane 

Relevant articles and documents

Method for synthesizing thioester through cross-coupling of visible light-catalyzed sodium sulfinate and acyl chloride

The method takes sodium sulfinate and acyl chloride as raw materials and utilizes 2, 6 - dimethyl -1, 4 - dihydro -3, 5 - pyridine dicarboxylic acid diethyl ester and an organic alkali catalytic system to cross-couple sulfur radicals and acyl radicals und

Metal-free thioesterification of amides generating acyl thioesters

A base-initiated thioesterification of amides with various thiols is reported. This reaction can take place efficiently under metal-free and air-atmospheric conditions, and provides a facile and practically useful approach to the synthesis of valuable acy

Oxalic Acid Monothioester for Palladium-Catalyzed Decarboxylative Thiocarbonylation and Hydrothiocarbonylation

Oxalic acid monothioester (OAM), an easily accessible and storable reagent, was reported herein as a thioester synthetic equivalent for palladium-catalyzed decarboxylative thiocarbonylation of organohalides and hydrothiocarbonylation of unsaturated carbon-carbon bonds at room temperature with high chemo- and regioselectivity. The reaction is applicable to the synthesis of cysteine-derived thioesters, thus allowing chemical modification of cysteine-containing peptides. Decarboxylation of OAM proceeds through oxidative addition of Pd(0) to the acyl-S bond, which accounts for the very mild reaction conditions.