39257-08-4Relevant articles and documents
Access to 1,2-diketones by an unusual radical cascade
Heng, Rama,Zard, Samir Z.
supporting information; experimental part, p. 3296 - 3298 (2011/05/05)
An unusual radical fragmentation of an unstrained cyclohexane structure was observed leading to complex 1,2-diketones.
Dependence of the Lewis Acid-induced Reaction of β-stannyl Ketones upon Substitution Pattern. 1,2-Alkyl Migration versus Cyclopropanation
Fujiwara, Jun,Yamamoto, Taro,Sato, Tadashi
, p. 1775 - 1778 (2007/10/02)
3-Stannylcyclohexanones fully substituted at 2 and 3 positions undergo a 1,2-alkyl migration and cyclopropanation.The balance of the reaction pattern depends upon the steric environment and migratory aptitude of the alkyl groups.
Cycloaliphatic unsaturated ketones as odour- and taste-modifying agents
-
, (2008/06/13)
Process for the preparation of unsaturated cycloaliphatic ketones useful as perfuming and odour-modifying agents in the manufacture of perfumes and perfumed products, and as flavouring and taste-modifying agents in the aromatization of foodstuffs in general and imitation flavours for foodstuffs, beverages, animal feeds, pharmaceutical preparations and tobacco products. Compositions of matter relating to some of said unsaturated cycloaliphatic ketones which are new, and perfume- and flavouring compositions containing same.