393562-47-5

Basic information

• Product Name: Benzaldehyde, 5-bromo-2-(2-ethenyl-5-oxo-1-pyrrolidinyl)-
• CAS NO: 393562-47-5
• Molecular Formula: C13H12BrNO2
• Molecular Weight: 294.148
• Mol File: 393562-47-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 5-bromo-2-(2-ethenyl-5-oxo-1-pyrrolidinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 5-bromo-2-(2-ethenyl-5-oxo-1-pyrrolidinyl)-(393562-47-5)
• EPA Substance Registry System: Benzaldehyde, 5-bromo-2-(2-ethenyl-5-oxo-1-pyrrolidinyl)-(393562-47-5)

Safety Data

• Hazardous Substances Data: 393562-47-5(Hazardous Substances Data)

Upstream product

• 52727-57-8 5-bromo-2-aminobenzoic acid methyl ester 
• 20712-12-3 (2-amino-5-bromophenyl)methanol 
• 393562-46-4 5-ethenyl-1-[4-bromo-2-(hydroxymethyl)phenyl]-2-pyrrolidinone 

Relevant articles and documents

Total synthesis of (+/-)-martinellic acid.

A 14-step synthesis of martinellic acid (1) that proceeds in 3% overall yield has been completed using the reaction of aniline 11 with Meldrum's acid-activated vinylcyclopropane 4 to give vinyl pyrrolidinone 12, condensation of aldehyde 13 with N-benzylglycine to form an azomethine ylide that cyclizes to give 14, selective reduction of 14 to amino alcohol 16 with LiBH(4) and MeOH, and guanidine formation by reaction of a cyanamide with 3-methyl-2-buten-1-amine in hexafluoro-2-propanol at 120 degrees C as key steps. [structure: see text]