394729-59-0

Basic information

• Product Name: (C₅H₅)Fe(C₅H₃)(PPh₂)(CHNCH(C₆H₄CH₃-p)Ph)
• Synonyms: (C₅H₅)Fe(C₅H₃)(PPh₂)(CHNCH(C₆H₄CH₃-p)Ph)
• CAS NO: 394729-59-0
• Molecular Weight: 577.489
• Mol File: 394729-59-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Fe(C₅H₃)(PPh₂)(CHNCH(C₆H₄CH₃-p)Ph)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Fe(C₅H₃)(PPh₂)(CHNCH(C₆H₄CH₃-p)Ph)(394729-59-0)
• EPA Substance Registry System: (C₅H₅)Fe(C₅H₃)(PPh₂)(CHNCH(C₆H₄CH₃-p)Ph)(394729-59-0)

Safety Data

• Hazardous Substances Data: 394729-59-0(Hazardous Substances Data)

Upstream product

• 1144039-25-7 (S)-α-(diphenylphosphino)ferrocenecarboxaldehyde 
• 55095-21-1 phenyl-p-tolylmethylamine 

Relevant articles and documents

Preparation and application of polymer-supported π-allylpalladium complex as a chiral catalyst in the asymmetric allylic alkylation

Chiral ferrocenylphosphine-imines A-D were synthesized and grafted to polystyrene to afford polymeric ligands PA-PD. Ligands A-D and PA-PD were used as ligands in the palladium-catalyzed asymmetric allylic alkylation. In the homogeneous reactions, the best result was obtained when the ligand A was used (99% yield and 82% ee). In the heterogeneous reactions, the highest ee value (73%) in the first run was obtained when PA was used as a ligand. Considering the enantioselectivity and reusability, the best result was obtained in the case of PC. The recycling of the polymer-supported π-allylpalladium catalyst gave unsatisfactory results: it can be reused three times with moderate enantioselectivities (60-70% ee).