395639-04-0

Basic information

• Product Name: bis(1,1-dimethylethyl)(2-iodo-4-nitrophenyl)imidocarbonate
• Synonyms: bis(1,1-dimethylethyl)(2-iodo-4-nitrophenyl)imidocarbonate
• CAS NO: 395639-04-0
• Molecular Weight: 464.257
• Mol File: 395639-04-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(1,1-dimethylethyl)(2-iodo-4-nitrophenyl)imidocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: bis(1,1-dimethylethyl)(2-iodo-4-nitrophenyl)imidocarbonate(395639-04-0)
• EPA Substance Registry System: bis(1,1-dimethylethyl)(2-iodo-4-nitrophenyl)imidocarbonate(395639-04-0)

Safety Data

• Hazardous Substances Data: 395639-04-0(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 6293-83-0 2-iodo-4-nitrophenylamine 

Downstream Products

• 171513-06-7 1,1-dimethylethyl (2-iodo-4-nitrophenyl)carbamate 

Relevant articles and documents

Diversely Substituted Quinolines via Rhodium-Catalyzed Alkyne Hydroacylation

The Rh-catalyzed hydroacylative union of aldehydes and o-alkynyl anilines leads to 2-aminophenyl enones, and onward to substituted quinolines. The mild reaction conditions employed in this chemistry result in a process that displays broad functional group

Indole-3-acetic acids and hetero analogues by one pot synthesis including Heck cyclisation

Bz-substituted indole-3-acetic acid ethyl esters (14e-g) and heteroanalogues, i.e. thienopyrroles (14a,c) and selenolopyrrole (14d), were prepared starting from N-BOC protected o-iodo aryl amines. Allylation with ethyl 4-bromocrotonate, followed by palladium-catalysed ring closure in a one pot reaction, yielded N-BOC protected indoles (13e-g), thienopyrroles (13a-c), and selenolopyrrole (13d). The BOC group was readily removed thermally after adsorption on silica. Oxothienopyrroles (11a-c) were similarly prepared.