39799-73-0

Basic information

• Product Name: Methyl 4-benzamidobenzoate
• Synonyms: Methyl 4-benzamidobenzoate
• CAS NO: 39799-73-0
• Molecular Formula: C₁₅H₁₃NO₃
• Molecular Weight: 255.26862
• Mol File: 39799-73-0.mol
• Article Data: 22

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Methyl 4-benzamidobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 4-benzamidobenzoate(39799-73-0)
• EPA Substance Registry System: Methyl 4-benzamidobenzoate(39799-73-0)

Safety Data

• Hazardous Substances Data: 39799-73-0(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 619-45-4 4-methoxycarbonyl aniline 
• 619-50-1 4-nitrobenzoic acid methyl ester 
• 201230-82-2 carbon monoxide 
• 71-43-2 benzene 
• 20442-96-0 methyl 4-azidobenzoate 
• 59501-97-2 potassium benzeneselenocarboxylate 
• 541-41-3 chloroformic acid ethyl ester 
• 65-85-0 benzoic acid 
• 591-50-4 iodobenzene 
• 13939-06-5 molybdenum hexacarbonyl 
• 1864-94-4 phenyl formate 
• 591-51-5 phenyllithium 
• 23138-53-6 methyl 4-isocyanatobenzoate 

Downstream Products

• 51774-36-8 methyl 4-(N-benzoyl-N-methylamino)benzoate 
• 582-80-9 p-benzamidobenzoic acid 
• 1035269-05-6 4-benzamido-N-[5-[2-(3-methoxyphenyl)ethyl]-2H-pyrazol-3-yl]benzamide 
• 136663-22-4 methyl 2-phenylbenzo[d]oxazole-6-carboxylate 
• 146305-29-5 N-[4-(hydrazinylcarbonyl)phenyl]benzamide 
• 5405-15-2 N-benzyl-N-(4-methylphenyl)amine 

Relevant articles and documents

Iron-catalyzed cross-coupling of N?methoxy amides and arylboronic acids for the synthesis of N-aryl amides

An efficient iron-catalyzed synthesis of N-aryl amides from N?methoxy amides and arylboronic acids is developed. FeCl3 is used as the sole catalyst for the cross-coupling reaction between N?methoxy amides and arylboronic acids without any other

Practical one-pot amidation of N -Alloc-, N -Boc-, and N -Cbz protected amines under mild conditions

A facile one-pot synthesis of amides from N-Alloc-, N-Boc-, and N-Cbz-protected amines has been described. The reactions involve the use of isocyanate intermediates, which are generated in situ in the presence of 2-chloropyridine and trifluoromethanesulfonyl anhydride, to react with Grignard reagents to produce the corresponding amides. Using this reaction protocol, a variety of N-Alloc-, N-Boc-, and N-Cbz-protected aliphatic amines and aryl amines were efficiently converted to amides with high yields. This method is highly effective for the synthesis of amides and offers a promising approach for facile amidation.

Palladium-Catalyzed Amidation and Amination of (Hetero)aryl Chlorides under Homogeneous Conditions Enabled by a Soluble DBU/NaTFA Dual-Base System

The palladium-catalyzed coupling of aryl and heteroaryl chlorides with primary amides under mild homogeneous reaction conditions is reported. Successful C-N coupling is enabled by the use of a unique "dual-base" system consisting of DBU and NaTFA, which serve as proton acceptor and halide scavenger, respectively, using low catalyst loadings (0.5 mol %) with readily available, air-stable palladium precatalysts. The DBU/NaTFA system also enables the room-temperature coupling of primary aryl amines with aryl chlorides and is tolerant of a variety of base-sensitive functional groups.