39815-00-4

Basic information

• Product Name: Benzene, 1-methyl-4-(1-propenylthio)-
• CAS NO: 39815-00-4
• Molecular Formula: C10H12S
• Molecular Weight: 164.271
• Mol File: 39815-00-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-(1-propenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-(1-propenylthio)-(39815-00-4)
• EPA Substance Registry System: Benzene, 1-methyl-4-(1-propenylthio)-(39815-00-4)

Safety Data

• Hazardous Substances Data: 39815-00-4(Hazardous Substances Data)

Upstream product

• 1516-28-5 allyl (p-tolyl)sulfide 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 161573-74-6 <(etoxycarbonyl)(4-methylphenylsulfinyl)methylene>triphenylphosphorane 
• 201230-82-2 carbon monoxide 
• 64-17-5 ethanol 
• 141-52-6 sodium ethanolate 

Downstream Products

• 22254-49-5 (E)-1-propenyl p-tolyl sulfoxide 
• 22254-48-4 (Z)-Propenyl-p-tolyl-vinyl-sulfoxid 

Relevant articles and documents

t-BuOK promoted stereoselective isomerization of allyl aryl ethers

The t-BuOK promoted stereoselective isomerization of allyl aryl ethers has been developed. The reactions proceeded well in methyl tert-butyl ether (MTBE), providing the corresponding products in good to excellent yields (83–96percent). Most of the substra

Insertion of Carbon Monoxide into Allylic Carbon-Sulfur Bonds Catalyzed by Palladium and Ruthenium Complexes

The metal complex-catalyzed insertion of carbon monoxide into the C-S bond of various allylic sulfides affords thioesters in up to 88percent yield.The reaction is catalyzed by various palladium complexes, with concomitant isomerization of the olefin into conjugation with the carbonyl group.In these cases, only the trans isomer was detected by 1H NMR spectroscopy.Ruthenium complexes also catalyzed the carbonylation but the initially formed β,γ-thioester was not isomerized.