39828-28-9

Basic information

• Product Name: Benzoic acid, 2,6-dihydroxy-4-methoxy-3-methyl-, methyl ester
• CAS NO: 39828-28-9
• Molecular Formula: C10H12O5
• Molecular Weight: 212.202
• Mol File: 39828-28-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2,6-dihydroxy-4-methoxy-3-methyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2,6-dihydroxy-4-methoxy-3-methyl-, methyl ester(39828-28-9)
• EPA Substance Registry System: Benzoic acid, 2,6-dihydroxy-4-methoxy-3-methyl-, methyl ester(39828-28-9)

Safety Data

• Hazardous Substances Data: 39828-28-9(Hazardous Substances Data)

Upstream product

• 4759-22-2 2,6-dihydroxy-4-methoxybenzoic acid 
• 95124-62-2 2,4,6-trihydroxy-3-methylbenzoic acid 
• 19722-76-0 methyl-2,6-dihydroxy-4-methoxybenzoate 
• 98442-51-4 3-Formyl-2,6-dihydroxy-4-methoxy-benzoesaeuremethylester 
• 186581-53-3 diazomethane 
• 39828-33-6 2,4,6-Trihydroxy-3-methyl-benzoesaeure-methylester 
• 98442-54-7 2,6-Dihydroxy-4-methoxy-3-methyl-benzoesaeure 
• 74-88-4 methyl iodide 

Downstream Products

• 55382-24-6 5-methoxy-4-methyl-resorcinol 
• 55382-30-4 2,4-Dihydroxy-6-methoxy-5-methyl-isobutyrophenon 
• 98442-54-7 2,6-Dihydroxy-4-methoxy-3-methyl-benzoesaeure 
• 67771-05-5 2,6-Dihydroxy-3-isobutyryl-4-methoxy-5-methyl-benzoesaeuremethylester 
• 21722-30-5 methyl 4-methoxy-3,5-dimethylphloroglucinol carboxylate 
• 118093-03-1 3-formyl-2,6-dihydroxy-4-methoxy-5-methyl-benzoic acid methyl ester 
• 125536-25-6 7-hydroxy-5-methoxy-6-methyl-2-phenyl-1-benzopyrylium perchlorate 
• 118093-05-3 2-methoxy-3-methyl-4,6-dihydroxybenzaldehyde 
• 99174-41-1 2.6.4'.6'-Tetrahydroxy-4.2'-dimethoxy-3.3'-dimethyl-5.5'-di-isobutyryl-diphenylmethan 
• 489-48-5 2.6.2'.4'-Tetrahydroxy-4.6'-dimethoxy-3.3'-dimethyl-5.5'-di-isobutyryl-diphenylmethan 
• 568-50-3 Methylen-bis-pseudoaspidinol-iBiB 
• 69480-06-4 1-(2,6-dihydroxy-4-methoxy-3-methylphenyl)ethan-1-one 

Relevant articles and documents

Enantioselective Total Synthesis of Berkeleyone A and Preaustinoids

Herein we report the first enantioselective total synthesis of 3,5-dimethylorsellinic acid-derived meroterpenoids (?)-berkeleyone A and its five congeners ((?)-preaustinoids A, A1, B, B1, and B2) in 12–15 steps, starting from commercially available 2,4,6-trihydroxybenzoic acid hydrate. Based upon the recognition of latent symmetry within D-ring, our convergent synthesis features two critical reactions: 1) a symmetry-breaking, diastereoselective dearomative alkylation to assemble the entire carbon core, and 2) a Sc(OTf)3-mediated sequential Krapcho dealkoxycarbonylation/carbonyl α-tert-alkylation to forge the intricate bicyclo[3.3.1]nonane framework. We also conducted our preliminary biomimetic investigations and uncovered a series of rearrangements (α-ketol, α-hydroxyl-β-diketone, etc.) responsible for the biomimetic diversification of (?)-berkeleyone A into its five preaustinoid congeners.

Trimethoxyphenyl Compounds, XI. Constituents of Hagenia abyssinica, 2: Synthesis of Phloracylophenones Containing One Phloroglucinol Unit

For the Koso constituents K6 and K8, we previously proposed the structures 1a, b and 2a, b.These assignments have been confirmed by synthesis. - Keywords: Flores koso, Revised Structure, Synthesis of Phloroglucinols