39847-43-3

Basic information

• Product Name: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide
• Synonyms: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide
• CAS NO: 39847-43-3
• Molecular Weight: 595.23
• Mol File: 39847-43-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide(39847-43-3)
• EPA Substance Registry System: N-methyl bis[(1,1,2,2,3,3,4,4,4-nonafluorobutane)sulfonyl]imide(39847-43-3)

Safety Data

• Hazardous Substances Data: 39847-43-3(Hazardous Substances Data)

Upstream product

• 39847-39-7 bis(nonafluorobutanesulfonyl)imide 
• 616-38-6 carbonic acid dimethyl ester 
• 186581-53-3 diazomethane 
• 1445-45-0 Trimethyl orthoacetate 
• 77-78-1 dimethyl sulfate 

Relevant articles and documents

Design of Electrophoretic and Biocompatible Poly(2-oxazoline)s Initiated by Perfluoroalkanesulfoneimides and Electrophoretic Deposition with Bioactive Glass

N-Methyl bis[(nonafluorobutane)sulfonyl]imide (Nf2NMe) was synthesized to serve as an initiator for polymerization of 2-oxazolines and the polymerization activity and control of molecular weight were compared with conventional methyl triflate (TfOMe). Ring-opening polymerization of the vinyl-containing 2-oxazoline, 2-(3-butenyl)-2-oxazoline, and a subsequent thiol-ene click reaction and oxidation resulted in the successful synthesis of electrophoretic poly(2-oxazoline)s containing pendent sulfone. It was possible to coat the polymeric sulfones obtained via oxone oxidation (conversion, >99%) on a stainless-steel anode selectively. Furthermore, hybridization of the poly(2-oxazoline)s with bioactive glass (Bioglass45S5) by electrophoretic deposition (EPD) was investigated, and the biocompatibility of the hybrid was also evaluated. (Figure Presented)

Direct methylation and trifluoroethylation of imidazole and pyridine derivatives

Direct methylation or trifluoroethylation of imidazole and pyridine derivatives using N-methyl bis((perfluoroalkyl)sul-fonyl)imides or trifluoroethyl phenyliodonium bis((trifluoromethyl)sulfonyl)imide affords high yields of the corresponding salts. This methodology provides a simple route to a variety of room temperature ionic liquids (RTILs).