39863-70-2Relevant articles and documents
Total synthesis of (±)-Scrodentoid A
Lv, Shao-Dong,Tian, Tian,Zhang, Liu-Qiang,Xu, Si-Yu,Zhao, Dong-Hai,Wang, Jun-Jie,Fu, Jian-Guo,Li, Yi-Ming,Feng, Chen-Guo
, (2019/11/26)
An efficient total synthesis of scrodentoid A was accomplished starting from a Hagemann's ester and a substituted (2-bromoethyl)benzene. Key reactions in this synthesis include C-alkylation of the Hagemann's ester, 6-endo-Trig cationic cyclization of an enone and Lewis acid promoted isomerization of a cis-fused ketone.
Synthesis of aromatic diterpenes synthesis of 12-hydroxy-abieta-8,11,13-trien-3,7-dione
Burnell,Caron
, p. 127 - 132 (2007/10/02)
Model studies involving cationic cyclisation of suitable dienes have provided a synthesis of the title compound. Preparation of the dienes from available aromatic starting materials and the modification of the cyclised products are described.