39880-26-7Relevant articles and documents
A formal total synthesis of (±)-homogynolide-B
Srikrishna, Adusumilli,Nagaraju, Sankuratri,Venkateswarlu, Somepalli,Hiremath, Uma S.,Reddy, T. Jagadeeswar,Venugopalan, Paloth
, p. 2069 - 2076 (1999)
A formal total synthesis of (±)-homogynolide-B, a sesquiterpene containing an α-spiro-β-methylene-γ-butyrolactone moiety spirofused to a bicyclo[4.3.0]nonane framework, is described. Thus, Hagemann's ester 11 was converted into the allyl alcohol 16 in thr
Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol
Srikrishna, Adusumilli,Vijaykumar, Dange
, p. 3295 - 3296 (2007/10/03)
Total synthesis of (±)-α-pinguisene 1 and (±)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.