399513-49-6

Basic information

• Product Name: Oxirane, [(1E)-2-(2-methoxyphenyl)ethenyl]-
• CAS NO: 399513-49-6
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 399513-49-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Oxirane, [(1E)-2-(2-methoxyphenyl)ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, [(1E)-2-(2-methoxyphenyl)ethenyl]-(399513-49-6)
• EPA Substance Registry System: Oxirane, [(1E)-2-(2-methoxyphenyl)ethenyl]-(399513-49-6)

Safety Data

• Hazardous Substances Data: 399513-49-6(Hazardous Substances Data)

Upstream product

• 399513-48-5 (+/-)-(3E)-1-chloro-4-(2-methoxy-phenyl)-but-3-en-2-ol 
• 60125-24-8 (E)-3-(2-methoxyphenyl)propenal 
• 2181-42-2 trimethylsulphonium iodide 

Downstream Products

• 722542-20-3 (+/-)-(1E)-1-(2-methoxyphenyl)hepta-1,6-dien-4-ol 
• 10542-87-7 (E)-4-(2-methoxyphenyl)but-3-en-2-one 
• 122801-57-4 2'-methoxy-(1,1'-biphenyl)-3-carbaldehyde 
• 1357163-00-8 (1E,4R,5S)-1-(2-methoxy-phenyl)-5-methylhepta-1,6-dien-4-ol 
• 1357163-01-9 (1E,4R,5R)-1-(2-methoxyphenyl)-5-methylhepta-1,6-dien-4-ol 

Relevant articles and documents

Nucleophilic Organic Base DABCO-Mediated Chemospecific Meinwald Rearrangement of Terminal Epoxides into Methyl Ketones

Nucleophilic organic base DABCO (1,4-diazabicyclo[2.2.2]octane)-mediated Meinwald rearrangement of various epoxides was investigated. 2-Aryl-, alkenyl-, and alkynylepoxides generate the corresponding methyl ketones chemospecifically in good to excellent yields. The current DABCO-mediated Meinwald rearrangement of epoxides features readily accessible starting materials, a wide substrate scope, a transition-metal- and acid-free environment, and chemospecificity in the isomerization of epoxides.

Chemoselective cross metathesis of bishomoallylic alcohols: Rapid access to fragment A of the cryptophycins

Equation presented. The racemic or enantioselective allylation of in situ formed β,γ-unsaturated aldehydes provides efficient access to bishomoallylic alcohols from readily available 2-vinyloxiranes. These products, when subjected to modified Grubbs cross