39952-67-5

Basic information

• Product Name: meso-3,4-diphenyl-hexane
• Synonyms: meso-3,4-diphenyl-hexane
• CAS NO: 39952-67-5
• Molecular Weight: 238.373
• Mol File: 39952-67-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: meso-3,4-diphenyl-hexane(CAS DataBase Reference)
• NIST Chemistry Reference: meso-3,4-diphenyl-hexane(39952-67-5)
• EPA Substance Registry System: meso-3,4-diphenyl-hexane(39952-67-5)

Safety Data

• Hazardous Substances Data: 39952-67-5(Hazardous Substances Data)

Upstream product

• 103-30-0 (E)-1,2-diphenyl-ethene 
• 103-65-1 phenylpropane 
• 934-11-2 (1-Chloro-propyl)-benzene 
• 925-90-6 ethylmagnesium bromide 
• 2114-36-5 1-bromopropylbenzene 
• 17714-42-0 1,3-dibromo-1-phenylpropane 
• 123-51-3 i-Amyl alcohol 
• 873973-22-9 2-ethyl-2,3-diphenyl-valeronitrile 
• 6114-57-4 (Z)-2,3-diphenylacrylonitrile 
• 38443-18-4 (E)-3,4-diphenylhex-3-ene 
• 94264-77-4 3,4-diphenylhexan-3-ol 
• 16282-16-9 1,2-diphenyl-butan-1-one 
• 873-66-5 1-propenylbenzene 
• 93-54-9 1-Phenyl-1-propanol 

Downstream Products

• 39952-68-6 meso-3.4-bis-(4-chloroacetyl-phenyl)-hexane 
• 15145-27-4 meso-3,4-bis-(4-amino-phenyl)-hexane 
• 4381-03-7 meso-α.α'-diethyl-bibenzyl-dicarbonitrile-(4.4') 
• 93-55-0 1-phenyl-propan-1-one 
• 6016-40-6 meso-3.4-bis-(4-acetyl-phenyl)-hexane 
• 94068-19-6 racem.-3.4-bis-(4-nitro-phenyl)-hexane 
• 94068-19-6 meso-3.4-bis-(4-nitro-phenyl)-hexane 
• 101881-40-7 meso-3,4-dicyclohexyl-hexane 

Relevant articles and documents

Ruthenium-Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism

The direct dehydrogenation of alkanes is among the most efficient ways to access valuable alkene products. Although several catalysts have been designed to promote this transformation, they have unfortunately found limited applications in fine chemical synthesis. Here, we report a conceptually novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst. The combination of a redox-active ligand and a sterically hindered aryl radical intermediate has unleashed this novel strategy. Importantly, mechanistic investigations have been performed to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.

Cathodic reductive couplings and hydrogenations of alkenes and alkynes catalyzed by the B12 model complex

The reductive coupling and hydrogenation of alkenes were catalyzed by the B12 model complex, heptamethyl cobyrinate perchlorate (1), in the presence of acid during electrolysis at??0.7?V vs. Ag/AgCl in acetonitrile. Conjugated alkenes showed a good reactivity during electrolysis to form reduced products. The product distributions were dependent on the substituents at the C[dbnd]C bond of the alkenes. ESR spin-trapping experiments using 5,5-dimethylpyrroline N-oxide (DMPO) revealed that the cobalt-hydrogen complex (Co–H complex) should be formed during the electrolysis and it functioned as an intermediate for the alkene reduction. The electrolysis was also applied to an alkyne, such as phenylacetylene, to form 2,3-diphenylbutane (racemic and meso) and ethylbenzene via styrene as reductive coupling and hydrogenated products, respectively.

SILVER(I)/ PERSULFATE OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS. ARYLACETIC ACID DIMERIZATION.

The oxidative decarboxylation of arylacetic acids by sodium persulfate and a catalytic amount of silver nitrate produces benzylic radicals which dimerize cleanly to give 1,2-diarylethanes.